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Question
Write the structure and IUPAC name of the major product in the following reaction.
\[\begin{array}{cc}
\ce{CH3 - CH - CH2Cl + NaI ->[Acetone]}\\
|\phantom{..................}\\
\ce{CH3\phantom{...............}}
\end{array}\]
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Solution
\[\begin{array}{cc}
\ce{CH3 - CH - CH2Cl + NaI ->[Acetone] CH3 - CH - CH2 - I + NaCl \downarrow}\\
\phantom{....}|\phantom{..................................}|\phantom{...................}\\
\ce{\underset{1-Chloro-2-methylpropane}{CH3}\phantom{................}
\ce{\underset{1-Iodo-2-methylpropane}{CH3}}\phantom{..............}}\\
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3 - CH - CH = CH2 + HBr ->[peroxide]}\\
|\phantom{........................}\\
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\end{array}\]
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