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Question
Write down the reactions taking place in different zones in the blast furnace during the extraction of iron.
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Solution
During the extraction of iron, the reduction of iron oxides takes place in the blast furnace. In this process, hot air is blown from the bottom of the furnace, and coke is burnt to raise the temperature up to 2200 K in the lower portion itself. The temperature is lower in the upper part. Thus, it is the lower part where the reduction of iron oxides (Fe2O3 and Fe3O4) takes place.
The reactions taking place in the lower temperature range (500 − 800 K) in the blast furnace are:
\[\ce{3Fe2O3 + CO -> 2Fe3O4 + CO2}\]
\[\ce{Fe3O4 + 4CO -> 3Fe + 4CO2}\]
\[\ce{Fe2O3 + CO -> 2FeO + CO2}\]
The reactions taking place in the higher temperature range (900-1500 K) in the blast furnace are:
\[\ce{C + CO2 -> 2CO}\]
\[\ce{FeO + CO -> Fe + CO2}\]
The silicate impurity of the ore is removed as slag by calcium oxide (CaO), which is formed by the decomposition of limestone (CaCO3)
\[\ce{CaCO3 -> CaO + CO2}\]
\[\ce{CaO + SiO2 -> \underset{(Slag)}{\underset{Calcium silicate}{CaSiO3}}}\]
RELATED QUESTIONS
The reaction,
Cr2O3 + 2Al → Al2O3 + 2Cr
(ΔGθ = -421kJ) is thermodynamically feasible as is apparent from the Gibbs energy value. Why does it not take place at room temperature?
Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?
Write chemical reactions taking place in the extraction of zinc from zinc blende.
State the role of silica in the metallurgy of copper.
The choice of a reducing agent in a particular case depends on thermodynamic factor. How far do you agree with this statement? Support your opinion with two examples.
How will you convert the following:
Zinc blende to Zinc metal
In the extraction of copper from its sulphide ore, the metal is formed by the reduction of \[\ce{Cu2O}\] with ______.
In the metallurgy of aluminium ______.
Choose the correct option of temperature at which carbon reduces \[\ce{FeO}\] to iron and produces \[\ce{CO}\].
Below point ‘A’ \[\ce{FeO}\] can ______.
The purest form of iron is prepared by oxidising impurities from cast iron in a reverberatory furnace. Which iron ore is used to line the furnace? Explain by giving reaction.
The mixture of compounds A and B is passed through a column of \[\ce{Al2O3}\] by using alcohol as eluant. Compound A is eluted in preference to compound B. Which of the compounds A or B, is more readily adsorbed on the column?
Explain the following:
Silica is added to the sulphide ore of copper in the reverberatory furnace.
Explain the following:
Carbon and hydrogen are not used as reducing agents at high temperatures.
A cuprous ore among the following is:-
Assertion: For the extraction of iron, haematite ore is used.
Reason: Haematite is a carbonate ore of iron.
