English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Which of the following statements are correct about this reaction? (i) The given reaction follows SN2 mechanism. (ii) (b) and (d) have opposite configuration. (iii) (b) and (d) have same

Advertisements
Advertisements

Question

Which of the following statements are correct about this reaction?

(i) The given reaction follows SN2 mechanism.

(ii) (b) and (d) have opposite configuration.

(iii) (b) and (d) have same configuration.

(iv) The given reaction follows SN1 mechanism.

Short/Brief Note
Advertisements

Solution

(i) The given reaction follows SN2 mechanism.

(ii) (b) and (d) have opposite configuration.

Explanation:

In the given reaction, alkyl halide is primary in nature. Here, a transitory state is observed in which one bond is broken and one bond is formed synchronously he., in one step. So, it follows SN2 mechanism.

In this mechanism, nucleophile attacks the carbon at 180° to the leaving group. So the reactant and product have opposite configuration.

shaalaa.com
  Is there an error in this question or solution?
Chapter 10: Haloalkanes and Haloarenes - Exercises [Page 140]

APPEARS IN

NCERT Exemplar Chemistry Exemplar [English] Class 12
Chapter 10 Haloalkanes and Haloarenes
Exercises | Q II. 33. | Page 140

RELATED QUESTIONS

Which would undergo SN1 reaction faster in the following pair and why?


How do you convert the following:

Ethanol to propanenitrile


In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction?


What are ambident nucleophiles? Explain with an example.


Out of C6H5CH2Cl and C6H5CHClC6H5, which is more easily hydrolysed by aqueous KOH.


What is the action of the following on ethyl bromide:
moist silver oxide


Which of the following is optically inactive?


The order of reactivity of the given haloalkanes towards nucleophile is:


Most reactive halide towards SN1 reaction is ____________.


Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of ____________.


Assertion: KCN reacts with methyl chloride to give methyl isocyanide.

Reason: CN is an ambident nucleophile.


A primary alkyl halide would prefer to undergo ______.


Ethylene chloride and ethylidene chloride are isomers. Identify the correct statements.

(i) Both the compounds form same product on treatment with alcoholic KOH.

(ii) Both the compounds form same product on treatment with aq.NaOH.

(iii) Both the compounds form same product on reduction.

(iv) Both the compounds are optically active.


Aryl halides are extremely less reactive towards nucleophilic substitution. Predict and explain the order of reactivity of the following compounds towards nucleophilic substitution:

(I)
(II)
(III)

When CH3CH2CHCl2 is treated NaNH2 product formed is:-


Which one of the following compounds is more reactive towards SN1 reaction?


Discuss SN2 mechanism of methyl bromide using aqueous KOH.


Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.

\[\begin{array}{cc}\ce{CH3CH2CHCH3}\\
\phantom{.....}|\\
\phantom{......}\ce{Br}\\
\end{array}\] or \[\begin{array}{cc}\phantom{.......}\ce{CH3}\\
\phantom{...}|\\
\ce{H3C - C - Br}\\
\phantom{...}|\\
\phantom{.......}\ce{CH3}\\
\end{array}\]


HCI, Major product ______.


The compound that will undergo SN1 reaction with the fastest rate is:


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×