English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Which of the following is not true about the voids formed in 3 dimensional hexagonal close packed structure? (i) A tetrahedral void is formed when a sphere of the second layer is present above

Advertisements
Advertisements

Question

Which of the following is not true about the voids formed in 3 dimensional hexagonal close packed structure?

(i) A tetrahedral void is formed when a sphere of the second layer is present above triangular void in the first layer.

(ii) All the triangular voids are not covered by the spheres of the second layer.

(iii) Tetrahedral voids are formed when the triangular voids in the second layer lie above the triangular voids in the first layer and the triangular shapes of these voids do not overlap.

(iv) Octahedral voids are formed when the triangular voids in the second layer exactly overlap with similar voids in the first layer.

Short/Brief Note
Advertisements

Solution

(iii) Tetrahedral voids are formed when the triangular voids in the second layer lie above the triangular voids in the first layer and the triangular shapes of these voids do not overlap.

(iv) Octahedral voids are formed when the triangular voids in the second layer exactly overlap with similar voids in the first layer.

Explanation:

Tetrahedral voids are formed when the triangular void in the second layer lie exactly above the triangular voids in the first layer and the triangular shape of these voids oppositely overlap.


Octahedral voids are formed when triangular void of second layer is not exactly overlap with similar void in first layer.


shaalaa.com
  Is there an error in this question or solution?
Chapter 1: Solid States - Exercises [Page 7]

APPEARS IN

NCERT Exemplar Chemistry Exemplar [English] Class 12
Chapter 1 Solid States
Exercises | Q II. 38. | Page 7

RELATED QUESTIONS

How will you distinguish between the following pair of terms?

Tetrahedral and octahedral voids


If the radius of the octahedral void is r and the radius of the atoms in close packing is R, derive the relation between r and R.


How many tetrahedral voids can exist per unit cell in a hexagonal close packing sphere?


Total number of voids in 0.5 mole of a compound which forms hexagonal close packed structure is ____________.


A compound is formed by two elements A and B. The element B forms cubic close packing and atoms of A occupy `1/3"rd"` of tetrahedral voids. The formula of this compound is ____________.


What is the coordination number of sodium in Na2O?


The Ca2+ and F are located in CaF2 crystal, respectively at face centered cubic lattice points and in ____________.


If AgI crystallises in zinc blende structure with I ions at lattice points. What fraction of tetrahedral voids is occupied by Ag+ ions?


Which set of following characteristics for ZnS crystal is correct?


Percentages of free space in cubic close packed structure and in the body-centered packed structure are respectively:


In which of the following crystals alternate tetrahedral voids are occupied?


The number of octahedral voids present in a lattice is A. The number of closed packed articles, the number of tetrahedral voids generated is B the number of closed packed particles:


In the hexagonal close-packed structure of a metallic lattice, the number of nearest neighbours of a metallic atom is ____________.


In which of the following arrangements octahedral voids are formed?

(i) hcp

(ii) bcc

(iii) simple cubic

(iv) fcc


The coordination number of Y will be in the XY types of crystal:


The number of tetrahedral voids per unit cell in NaCl crystal is:

(i) 4

(ii) 8

(iii) twice the number of octahedral voids.

(iv) four times the number of octahedral voids.


Show that in a cubic close packed structure, eight tetrahedral voids are present per unit cell.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×