Advertisements
Advertisements
Question
The elementary reaction \[\ce{O3_{(g)} + O_{(g)} -> 2O2_{(g)}}\] is ______.
Options
unimolecular and second order
bimolecular and first order
bimolecular and second order
unimolecular and first order
Advertisements
Solution
The elementary reaction \[\ce{O3_{(g)} + O_{(g)} -> 2O2_{(g)}}\] is bimolecular and second order.
APPEARS IN
RELATED QUESTIONS
Choose the most correct option.
Slope of the graph ln[A]t versus t for first-order reaction is _________.
Choose the most correct option.
Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.
Choose the most correct option.
For an endothermic reaction, X ⇌ Y. If Ef is the activation energy of the forward reaction and Er that for the reverse reaction, which of the following is correct?
Answer the following in brief.
For the reaction 2A + B → products, find the rate law from the following data.
| [A]/M | [B]/M | rate/M s-1 |
| 0.3 | 0.05 | 0.15 |
| 0.6 | 0.05 | 0.30 |
| 0.6 | 0.2 | 1.20 |
Answer the following in one or two sentences.
For the reaction,
\[\ce{CH3Br_{(aq)} + OH^-_{ (aq)} -> CH3OH^-_{ (aq)} + Br^-_{ (aq)}}\], rate law is rate = k`["CH"_3"Br"]["OH"^-]`
What is the change in rate if concentrations of both reactants are doubled?
A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is _______.
The rate law relates to the rate of a chemical reaction in terms of _______.
Define order of reaction with suitable examples.
A reaction occurs in the following steps:
Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)
Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)
- Write the equation of overall reaction.
- Write the rate law.
- Identify reaction intermediate.
For the reaction 2A + B → C, rate of disappearance of A 0.076 mol s –1.
- What is the rate of formation of C?
- What is the rate of consumption of B?
- What is the rate of the overall reaction?
In a first-order reaction A → B, 60% of a given sample of a compound decomposes in 45 mins. What is the half-life of reaction? Also, write the rate law equation for the above first-order reaction.
The rate constant of a first order reaction whose half-life is 480 seconds, is ____________.
For the non-stoichiometric reaction
\[\ce{2A + B -> C + D}\], the following kinetic data were obtained in three separate experiments, all at 298 K.
| Initial concentration (A) |
Initial concentration (B) |
Initial rate of formation of C (mol dm−3 s−1) |
| 0.1 M | 0.1 M | 1.2 × 10−3 |
| 0.1 M | 0.2 M | 1.2 × 10−3 |
| 0.2 M | 0.1 M | 2.4 × 10−3 |
The rate law for the formation of C is:
For a chemical reaction rate law is, rate = k[A]2[B]. If [A] is doubled at constant [B], the rate of reaction ______.
For a hypothetical reaction \[\ce{A + B -> C}\], it is found that doubling the concentration of A increases the rate by 8 times and doubling the concentration of B increases the rate by 4 times. The overall order of the reaction is ____________.
The rate law for the reaction \[\ce{A + B + C -> Product}\] is expressed as Rate = k[A]2 [B]1 [C]0. What is the overall order of the reaction?
Consider the reaction \[\ce{2A + 2B -> C + 2D}\], if concentration of A is doubled at constant [B], rate increases by a factor 4. If concentration B is doubled at constant [A] the rate is doubled. Rate law of the reaction is ____________.
The reaction \[\ce{A + B -> P}\], is second order in A and first order in B. What is the rate law for the reaction?
What is the order of reaction for decomposition of gaseous acetaldehyde?
For the reaction \[\ce{4NH3 + 5O2 -> 4NO + 6H2O}\], the rate of disappearance of NH3 is 3.6 × 10-3 M/s. What is the rate of formation of water?
Which of the following unit is used to express the rate of a reaction?
Write the rate law for the following reaction:
A reaction that is second order in NO and first order in Br2.
For a chemical reaction A → 7 products, the rate of reaction doubles when the concentration of A is increased by a factor 4. The order of the reaction is ______.
The rate constant for the reaction,
2N2O5(g) → 2N2O4(g) + O2(g) is 4.98 × 10-4 s-1.
What is the order of reaction?
The rate constant for a first-order reaction whose half-life is 480 seconds is ______.
