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Question
Suggest the most important type of intermolecular attractive interaction in the following pair.
Methanol and acetone
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Solution
Dipole-dipole interactions, because both are polar.
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Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot `p_"total"`, `p_"chloroform"` and `p_"acetone"` as a function of `chi_"acetone"`. The experimental data observed for different compositions of mixtures is:
| `bb(100 xx chi_"acetone")` | `bb(P_"acetone"//"mm Hg")` | `bb(p_"chloroform"//"mm Hg")` |
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| 72.1 | 521.1 | 120.7 |
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