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Question
Show how the following compound can be converted to benzoic acid.
Ethylbenzene
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Solution
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Which is the most suitable reagent for the following conversion?
\[\begin{array}{cc}
\phantom{....................}\ce{O}\phantom{.....................................}\ce{O}\phantom{.}\\
\phantom{....................}||\phantom{......................................}||\phantom{.}\\
\phantom{}\ce{CH3 - CH = CH - CH2 - C - CH3 -> CH3 - CH = CH - CH2 - C - OH}\phantom{.}
\end{array}\]
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(i) Grignard reaction
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Match the reactions given in Column I with the suitable reagents given in Column II.
| Column I (Reactions) |
Column II (Reagents) |
| (i) Benzophenone Diphenylmethane | (a) \[\ce{LiAlH4}\] |
| (ii) Benzaldehyde 1-Phenylethanol | (b) \[\ce{DIBAL-H}\] |
| (iii) Cyclohexanone Cyclohexanol | (c) \[\ce{Zn(Hg)/Conc. HCl}\] |
| (iv) Phenyl benzoate Benzaldehyde | (d) \[\ce{CH3MgBr}\] |
Substitution of one alkyl group by replacing hydrogen of primary amines
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