English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Rate law for the reaction A+2B⟶C is found to be Rate = k [A][B]. Concentration of reactant ‘B’ is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be ______. - Chemistry

Advertisements
Advertisements

Question

Rate law for the reaction \[\ce{A + 2B -> C}\] is found to be Rate = k [A][B]. Concentration of reactant ‘B’ is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be ______.

Options

  • the same

  • doubled

  • quadrupled

  • halved

MCQ
Fill in the Blanks
Advertisements

Solution

Rate law for the reaction \[\ce{A + 2B -> C}\] is found to be Rate = k [A][B]. Concentration of reactant ‘B’ is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be the same.

Explanation:

The rate of concentration of a reaction does not depend upon the concentrations of the reactants. Hence, it will remain the same. Even if the equation shows the double concentration level, even the rate concentration doubles so it's the same throughout.

Following with the equation \[\ce{A + 2B -> C}\] 

If rate considered as (1) Rate1 = k[A][B]

If rate considered as 2

Then, Rate1 = k[A][2B]

Rate2 = 2Rate1 

shaalaa.com
  Is there an error in this question or solution?
Chapter 4: Chemical Kinetics - Exercises [Page 51]

APPEARS IN

NCERT Exemplar Chemistry [English] Class 12
Chapter 4 Chemical Kinetics
Exercises | Q I. 14. | Page 51

RELATED QUESTIONS

Define “zero order reaction”.


A → B is a first order reaction with rate 6.6 × 10-5m-s-1. When [A] is 0.6m, rate constant of the reaction is

  • 1.1 × 10-5s-1
  • 1.1 × 10-4s-1
  • 9 × 10-5s-1
  • 9 × 10-4s-1

A reaction is second order in A and first order in B.

(i) Write the differential rate equation.

(ii) How is the rate affected on increasing the concentration of A three times?

(iii) How is the rate affected when the concentrations of both A and B are doubled?

 


For a reaction: 

Rate = k

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.


From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.

\[\ce{CH3CHO_{(g)} -> CH4_{(g)} + CO_{(g)}}\] Rate = k [CH3CHO]3/2


Mention the factors that affect the rate of a chemical reaction.


For a reaction R ---> P, half-life (t1/2) is observed to be independent of the initial concentration of reactants. What is the order of reaction?


Rate of reaction for the combustion of propane is equal to:

\[\ce{C3H8_{(g)} + 5O2_{(g)} -> 3CO2_{(g)} + 4H2O_{(g)}}\]


In any unimolecular reaction:

(i) only one reacting species is involved in the rate determining step.

(ii) the order and the molecularity of slowest step are equal to one.

(iii) the molecularity of the reaction is one and order is zero.

(iv) both molecularity and order of the reaction are one.


Assertion: Order of the reaction can be zero or fractional.

Reason: We cannot determine order from balanced chemical equation.


Use Molecular Orbital theory to determine the bond order in each of species, [He2j+ and [He2]2+?


A catalyst in a reaction changes which of the following?


For a reaction R → p the concentration of reactant change from 0.03 m to 0.02 m in minute, calculate the average rate of the reaction using the unit of second.


For a reaction \[\ce{Cl2l(g) + 2No(g) -> 2NaCl(g)}\] the rate law is expressed as rate= K[Cl2] [No]2 what is the order of the reaction?


For reaction 2A + B → BC + D which of the following does not Express the reaction rates


Identify the order of reaction from the following unit for its rate constant:

L mol–1 s–1


The conversion of molecules A to B follow second order kinetics. If concentration of A is increased to three times, how will it affect the rate of formation of B?


For a chemical reaction starting with some initial concentration of reactant At as a function of time (t) is given by the equation,

`1/("A"_"t"^4) = 2 + 1.5 xx 10^-3` t

The rate of disappearance of [A] is ____ × 10-2 M/sec when [A] = 2 M.

[Given: [At] in M and t in sec.]
[Express your answer in terms of 10-2 M /s]
[Round off your answer if required]


Which of the following statement is true?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×