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Karnataka Board PUCPUC Science 2nd PUC Class 12

Predict all the alkenes that would be formed by dehydrohalogenation of the following halide with sodium ethoxide in ethanol and identify the major alkene: 2, 2, 3-Trimethyl-3-bromopentane

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Question

Predict all the alkenes that would be formed by dehydrohalogenation of the following halide with sodium ethoxide in ethanol and identify the major alkene:

2, 2, 3-Trimethyl-3-bromopentane

Short Answer
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Solution

There are two different types of β-hydrogen atoms present in the halide. Hence, in the dehydrohalogenation reaction, it will form two alkenes: 3, 4, 4-trimethylpent-2-ene and 2-ethyl-3, 3-dimethylbut-1-ene. The first alkene is more stable because it is more substituted (according to the Saytzeff rule). Hence, it is the major product.

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Chapter 6: Haloalkanes and Haloarenes - Exercises [Page 190]

APPEARS IN

NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 6 Haloalkanes and Haloarenes
Exercises | Q 6.10 (iii) | Page 190
Nootan Chemistry [English] Class 12 ISC
Chapter 6 Haloalkanes and Haloarenes
SHORT ANSWER TYPE QUESTIONS | Q 45. (e) | Page 612

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