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प्रश्न
Predict all the alkenes that would be formed by dehydrohalogenation of the following halide with sodium ethoxide in ethanol and identify the major alkene:
2, 2, 3-Trimethyl-3-bromopentane
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उत्तर
There are two different types of β-hydrogen atoms present in the halide. Hence, in the dehydrohalogenation reaction, it will form two alkenes: 3, 4, 4-trimethylpent-2-ene and 2-ethyl-3, 3-dimethylbut-1-ene. The first alkene is more stable because it is more substituted (according to the Saytzeff rule). Hence, it is the major product.
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संबंधित प्रश्न
Identify the product ‘D’ in the following sequence of reactions:
\[\ce{H3C - CH2 - CH2 - Cl \underset{KOH}{\overset{Alc}{->}} 'B' \overset{HBr}{->} 'C' \underset{Elther}{\overset{Na}{->}}'D'}\]
Identify ‘A’ and ‘B’ in the following reaction :
\[\ce{CH3 - CH = CH2 ->[HBr]'A' ->[alc.KOH]'B'}\]
Predict all the alkenes that would be formed by dehydrohalogenation of the following halide with sodium ethoxide in ethanol and identify the major alkene:
2-Chloro-2-methylbutane
Write the structure of the major organic product in the following reaction:
\[\ce{(CH3)3CBr + KOH ->[ethanol][heat]}\]
How the following conversion can be carried out?
1-Bromopropane to 2-bromopropane
How the following conversion can be carried out?
2-Chloropropane to 1-propanol
How the following conversion can be carried out?
2-Bromopropane to 1-bromopropane
Draw a neat, labelled energy profile diagram for SN1 reaction mechanism.
What are racemates?
Observe the following compounds and answer the questions given below.
(I)
\[\ce{\underset{\text{(II)}}{CH3 - CH2 - Br}}\]
- Identify the type of halides.
- Explain the nature of the C – Br bond in both of these halides.
- Which of these compounds will undergo aqueous alkaline hydrolysis readily? Write the reaction in support of your answer.
Identify the major product formed when 2-cyclohexylchloroethane undergoes a dehydrohalogenation reaction. Name the reagent which is used to carry out the reaction.
Elimination of bromine from 2-bromobutane results in the formation of ______.
The conversion of an alkyl halide into an alkene by alcoholic KOH is classified as ______.
A primary alkyl halide would prefer to undergo ______.
Reaction of trans-2-phenyl-1-bromocyclopentane with alcoholic KOH produces.
Which of the following alkyl halides will undergo SN1 reaction most readily?
An SN1 reaction at the asymmetric carbon of an enantiomerically pure chiral alkyl halide gives a product ______.
