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How Can These Impurities Be Removed?

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Question

How can these impurities be removed? 

Answer in Brief
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Solution

  1. The impurities can be removed from hydrogen by passing it through
  1. Silver nitrate solution to remove arsine and phosphine.

    AsH3 + 6AgNO3 → Ag3As + 3AgNO3 + 3HNO3

    PH+ 6AgNO→ Ag3P + 3AgNO3 + 3HNO3

  1. Lead nitrate solution to remove hydrogensulphide.

    Pb(NO3)2 + H2S → Pbs + 2HNO3

  1. Caustic potash solution to remove sulphur dioxide, carbon dioxide and oxides of nitrogen.

    SO2 + 2KOH → K2SO3 + H2O

    CO2 + 2KOH→ K2CO3+ H2O

    2NO2 + 2KOH →KNO2 + KNO3 + H2O

  1. A drying agent used to dry the gas. Common drying agents such as fused calcium chloride, caustic potash stick and phosphorus pentoxide remove water vapor.

So, the gas is purified and dried and then collected over mercury because mercury does not react with it. 

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Recognition and Identification of Gases
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Chapter 6: Study of the First Element - Hydrogen - Exercise 6 (B) [Page 105]

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Selina Concise Chemistry [English] Class 9 ICSE
Chapter 6 Study of the First Element - Hydrogen
Exercise 6 (B) | Q 3.2 | Page 105
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