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प्रश्न
How can these impurities be removed?
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उत्तर
- The impurities can be removed from hydrogen by passing it through
- Silver nitrate solution to remove arsine and phosphine.
AsH3 + 6AgNO3 → Ag3As + 3AgNO3 + 3HNO3
PH3 + 6AgNO3 → Ag3P + 3AgNO3 + 3HNO3
- Lead nitrate solution to remove hydrogensulphide.
Pb(NO3)2 + H2S → Pbs + 2HNO3
- Caustic potash solution to remove sulphur dioxide, carbon dioxide and oxides of nitrogen.
SO2 + 2KOH → K2SO3 + H2O
CO2 + 2KOH→ K2CO3+ H2O
2NO2 + 2KOH →KNO2 + KNO3 + H2O
- A drying agent used to dry the gas. Common drying agents such as fused calcium chloride, caustic potash stick and phosphorus pentoxide remove water vapor.
So, the gas is purified and dried and then collected over mercury because mercury does not react with it.
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संबंधित प्रश्न
Give reason for the following:
Nitric acid not used for the preparation of hydrogen gas?
Name the following:
A metal which liberates hydrogen only when steam is passed over red hot metal.
Name the following:
A metallic oxide which can be reduced into metal by hydrogen.
Name the chemicals required to prepare hydrogen gas in the laboratory.
FILL IN THE BLANK
Sodium liberates hydrogen when treated with cold .............
Give reason:
Apparatus for laboratory preparation of hydrogen should be airtight and away from a naked flame.
How would you show that hydrogen is lighter than air?
Starting from zinc how would you obtain hydrogen using a dilute acid.
[Give balanced equation & name the product formed in the case other than hydrogen].
Name a metal which will not react with the reactants above to give hydrogen.
Starting from zinc how would you obtain hydrogen using an alkali.
[Give balanced equation & name the product formed in the case other than hydrogen].
Name a metal which will not react with the reactants above to give hydrogen.
In the laboratory preparation of hydrogen from zinc & dilute hydrocholoric acid – state a reason for the collecting the hydrogen by downward displacement of water and not air & collecting it after all the air in the apparatus is allowed to escape.
Give a balanced equation for the following conversions sodium aluminate from aluminium.
In the laboratory preparation of hydrogen from zinc and dil. acid. Give a reason for the following:
The complete apparatus is air-tight.
In the laboratory preparation of hydrogen from zinc and dil. acid. Give a reason for the following:
The lower end of the thistle funnel should dip below the level of the acid in the flask.
Give a reason for the following.
Nitric acid in the dilute form is not used in the laboratory preparation of hydrogen from metals.
Name the following.
A gaseous reducing agent which is basic in nature.
The diagram represent the preparation and collection of hydrogen by a standard laboratory method.
Name a solution which absorbs the impurity – `"H"_2"S"`
The diagram represent the preparation and collection of hydrogen by a standard laboratory method.
State, why hydrogen is collected after all the air in the apparatus, is allowed to escape.
