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Karnataka Board PUCPUC Science 2nd PUC Class 12

Give reason for the higher boiling point of ethanol in comparison to methoxymethane.

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Question

Give reason for the higher boiling point of ethanol in comparison to methoxymethane.

Chemical Equations/Structures
Give Reasons
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Solution

Ethanol undergoes intermolecular H-bonding due to the presence of −OH group, resulting in the association of molecules. Extra energy is required to break these hydrogen bonds. On the other hand, methoxymethane does not undergo H-bonding. Therefore, ethanol has a higher boiling point than methoxymethane.

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Chapter 7: Alcohols, Phenols and Ethers - Exercises [Page 223]

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NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 7 Alcohols, Phenols and Ethers
Exercises | Q 7.22 | Page 223
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