English

For a reaction A + B ⟶ P, the rate is given by Rate = k [A] [B]2. How is the rate of reaction affected if the concentration of B is doubled? - Chemistry

Advertisements
Advertisements

Question

For a reaction A + B ⟶ P, the rate is given by

Rate = k [A] [B]2

How is the rate of reaction affected if the concentration of B is doubled?

Advertisements

Solution 1

For a reaction, A + B⟶ P

Rate1 = k[A][B]2

If the concentration of B is doubled

Rate2 = k[A][2B]2

Rate1 = k[A][B]2

Rate2 = k[A][2B]2

Rate1 = B2

Rate2 4B2

Rate2 = 4 Rate1

The rate of reaction will be four times the initial rate.

shaalaa.com

Solution 2

A + B → P

Rate = k[A] [B]2

Since the given reaction has order two with respect to reactant B, thus, if the concentration of B is doubled in the given reaction, then the rate of reaction will become four times.

shaalaa.com
  Is there an error in this question or solution?
2014-2015 (March) Panchkula Set 1

Video TutorialsVIEW ALL [1]

RELATED QUESTIONS

From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.

\[\ce{CH3CHO_{(g)} -> CH4_{(g)} + CO_{(g)}}\] Rate = k [CH3CHO]3/2


A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is doubled?


The decomposition of N2O5(g) at 320K according to the following equation follows first order reaction:

`N_2O_(5(g))->2NO_(2(g))+1/2O_(2(g))`

The initial concentration of N2O5(g) is 1.24 x 10-2 mol. L-1 and after 60 minutes 0.20x10-2 molL-1. Calculate the rate constant of the reaction at 320K.


Which of the following statement is true for order of a reaction?


Rate law for the reaction \[\ce{A + 2B -> C}\] is found to be Rate = k [A][B]. Concentration of reactant ‘B’ is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be ______.


Why can we not determine the order of a reaction by taking into consideration the balanced chemical equation?


Match the graph given in Column I with the order of reaction given in Column II. More than one item in Column I may link to the same item of Column II.

  Column I Column II
(i)  
(ii)  (a) 1st order
(iii) (b) Zero-order
(iv)    

The rate constant for the reaction \[\ce{2H2O5 -> 4NO2 + O2}\] is 30 × 10–5 sec–1. if the rate is 204 × 10–5 mol L1 S1, then the concentration of N2O5 (in mol1) is-


For the reaction, \[\ce{A +2B → AB2}\], the order w.r.t. reactant A is 2 and w.r.t. reactant B. What will be change in rate of reaction if the concentration of A is doubled and B is halved?


Assertion (A): Order of reaction is applicable to elementary as well as complex reactions.

Reason (R): For a complex reaction, molecularity has no meaning.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×