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Question
Figure shows three paths through which a gas can be taken from the state A to the state B. Calculate the work done by the gas in each of the three paths.

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Solution
Work done during any process, W = P ∆ V
If both pressure and volume are changing during a process, then work done can be found out by finding the area under the PV diagram.
In path ACB, for line AC :-
Since initial volume is equal to final volume,
∆ V = 0
⇒ WAC = P ∆ V = 0
For line BC :-
P = 30 × 103 pa
WACB = WAC + WBC = 0 + P∆V
= 30 × 103 × (25 − 10) × 10−6
= 0.45 J
For path AB:-
Since both pressure and volume are changing, we use the mean pressure to find the work done.
Mean pressure, P = \[\frac{1}{2} \times (30 + 10) \times {10}^3\]
WAB = \[\frac{1}{2}\]× (10 + 30) × 103 × 15 × 10−6
= \[\frac{1}{2}\] × 40 × 15 × 10−3 = 0.30 J
Initial volume in path ADB, along line DB is the same as final volume. Thus, work done along this line is zero.
Along line AD, P = 10 kPa
W = WAD + WDB
= 10 × 103 (25 − 10) × 10−6 + 0
= 10 × 15 × 10−3 = 0.15 J
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