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Question
A gas is taken through a cyclic process ABCA as shown in figure. If 2.4 cal of heat is given in the process, what is the value of J ?

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Solution
Heat given in the process, ∆Q = 2.4 cal
∆W = WAB + WBC + WCA
For line AB:-
Change in volume,
ΔV = 0
∴ WAB = 0
For line BC :-
Mean pressure, \[P = \frac{1}{2} \times (100 + 200) kPa = 150 \times {10}^3 Pa\]
\[ ∆ V = (700 - 500) cc = 200 cc\]
\[ W_{BC} = 150 \times {10}^3 \times 200 \times {10}^{- 6} \]
\[ W_{BC} = 30 J\]
For line AC :-
P = 100 kPa
ΔV = 200 cc
WCA = 100 × 103 × 200 × 10−6
Total work done in the one cycle is given by
∆W = 0 + 150× 103 × 200 × 10−6 − 100 × 103 × 200 × 10−6
∆W = `1/2` × 300 × 103 × 200 × 10−6 − 20
∆W = 30 J − 20 J = 10 J
∆U = 0 .............(in a cyclic process)
∆Q = ∆U + ∆W
⇒ 2.4J = 10
\[\Rightarrow J = \frac{10}{2 . 4} = \frac{100}{24} = \frac{25}{6} = 4 . 17 \text{J/cal}\]
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