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Question
Define a homologous series. Give the name and structural formula of one homologue of the following:
CH3OH
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Solution
Homologous series: A series of organic compounds having similar structures and chemical properties and in which the successive compounds differ by -CH2 group is called a homologous series. A homologue of CH3OH will differ by the -CH2 group; therefore, methanol's successive homologue will be ethanol (C2H5OH).
The structural formula of ethanol is as follows:
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RELATED QUESTIONS
Write the molecular formula of first two members of homologous series having functional group -Cl.
The following vegetables are kept in a basket :
Potato, Tomato, Radish, Brinjal, Carrot, Bottle-gourd
Which two of these vegetables correctly represent the homologous structures?
(A) Carrot and Tomato
(B) Potato and Brinjal
(C) Radish and Carrot
(D) Radish and Bottle-gourd
Give the molecular formula of one homologue of each of the following:
C2H6
Write the molecular formula of the third member of the homologous series of carbon compounds with general formula CnHO2n+1OH.
The molecular formula of a homologue of butane is:
(a) C4H8
(b) C3H6
(c) C4H6
(d) C3H8
The number of carbon atoms present in the molecule of fifth member of the homologous series of alkynes is:
(a) four
(b) five
(c) six
(d) seven
A colourless organic liquid X of molecular formula C2H4O2 turns blue litmus to red. Another colourless organic liquid Y of molecular formula C3H6O has no action on any litmus but it is used as a nail polish remover. A yet another colourless organic liquid Z of molecular formula C2H6O has also no action on litmus but it is used in tincture of iodine.
(a) Name the liquid X. To which homologous series does it belong? Give the name of another member of this homologous series.
(b) Name the liquid Y. To which homologous series does it belong? Write the name of another member of this homologous series.
(c) Can you name an organic compound having the same molecular formula as liquid Y but which belongs to a different homologous series? What is this homologous series?
(d) Name the liquid Z. To which homologous series does it belong? Write the name of another member of this homologous series.
Succeeding members of a homologous series differ by ______.
Give the structure of the second member of the alcohol group.
Write names of first four homologous series of alcohols.
Give the names of the first four members of the homologous series of
alkynes.
Complete the correlation:
Alkene : C = C :: Alkyne: _______.
While going in an increasing order there is a rise in the molecular mass of the consecutive members of the homologous series by _______.
The general molecular formula for the homologous series of alkynes is _______.
Complete the following table for homologous series of alcohols.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methanol | CH4O | CH3-OH | 1 | 1 | 63 |
| Ethanol | C2H6O | CH3–CH2-OH | 2 | 2 | 78 |
| Propanol | C3H8O | CH3–CH2–CH2-OH | ______ | ______ | 97 |
| Butanol | C4H10O | CH3–CH2–CH2–CH2–OH | ______ | ______ | 118 |
Complete the following table for homologous series of Alkenes.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Ethene | C2H4 | CH2 = CH2 | 2 | 0 | -102 |
| Propene | C3H6 | CH3–CH = CH2 | 3 | 1 | -48 |
| 1-Butene | C4H8 | CH3–CH2–CH = CH2 | ______ | ______ | -6.5 |
| 1-Pentene | C5H10 | CH3–CH2–CH2–CH = CH2 | ______ | ______ | 30 |
Consider the carbon compounds having following molecular formula:
(i) C3H6 (ii) C3H8 (iii) C4H6 (iv) C6H6 (v) C6H12
- State the number of double covalent bonds present in C3H8.
- Write the formula of first member of the homologous series to which the carbon compound C4H6 belongs.
- Which one of the above compounds forms a ring structure of carbon atoms?
- Identify, which of the above compounds, is a member of alkane series.
Name and draw the electron dot structure of first homologue of alkynes series.
