English
Karnataka Board PUCPUC Science Class 11

At 500 K, equilibrium constant, KXc, for the following reaction is 5. 12HX2(g)+12IX2(g)↽−−⇀HI(g) What would be the equilibrium constant KXc for the reaction 2HI(g)↽−−⇀HX2(g)+IX2(g)

Advertisements
Advertisements

Question

At 500 K, equilibrium constant, \[\ce{K_c}\], for the following reaction is 5.

\[\ce{1/2 H2 (g) + 1/2 I2 (g) ⇌ HI (g)}\]

What would be the equilibrium constant \[\ce{K_c}\] for the reaction

\[\ce{2HI (g) ⇌ H2 (g) + I2 (g)}\]

Options

  • 0.04

  • 0.4

  • 25

  • 2.5

MCQ
Advertisements

Solution

0.04

Explanation:

If the equation is multiplied by 2, the equilibrium constant for the new equation is the square of \[\ce{K}\] it means we must do the square of 5 that is 25. Then and on reversing the reaction the value of the equilibrium constant is inversed means the value of K comes out to be 1/25 = 0.04. 

shaalaa.com
Law of Chemical Equilibrium and Equilibrium Constant
  Is there an error in this question or solution?
Chapter 7: Equilibrium - Multiple Choice Questions (Type - I) [Page 89]

APPEARS IN

NCERT Exemplar Chemistry Exemplar [English] Class 11
Chapter 7 Equilibrium
Multiple Choice Questions (Type - I) | Q 18 | Page 89

RELATED QUESTIONS

Write the expression for the equilibrium constant, Kc for each of the following reactions:

\[\ce{2NOCl (g) ⇌ 2NO (g) + Cl2 (g)}\]


Write the expression for the equilibrium constant, Kc for the following reactions:

\[\ce{2Cu(NO3)2 (s) ⇌ 2CuO (s) + 4NO2 (g) + O2 (g)}\]


Write the expression for the equilibrium constant, Kc for the following reactions:

\[\ce{CH3COOC2H5(aq) + H2O(l) ⇌CH3COOH (aq) + C2H5OH (aq)}\]


Write the expression for the equilibrium constant, Kc for the following reactions

\[\ce{I2 (s) + 5F2 ⇌ 2IF5}\]


A reaction between N2 and O2 takes place as follows:

\[\ce{2N2 (g) + O2 (g) ⇌ 2N2O (g)}\]

If a mixture of 0.482 mol of N2 and 0.933 mol of O2 is placed in a 10 L reaction vessel and allowed to form N2O at a temperature for which Kc = 2.0 × 10-37, determine the composition of equilibrium mixture.


Kp = 0.04 atm at 899 K for the equilibrium shown below. What is the equilibrium concentration of C2H6 when it is placed in a flask at 4.0 atm pressure and allowed to come to equilibrium?

\[\ce{C2H6 (g) ⇌ C2H4 (g) + H2 (g)}\]


Calculate a) ΔG°and b) the equilibrium constant for the formation of NO2 from NO and O2 at 298 K

\[\ce{NO(g) + 1/2 O_2 (g) <=> NO_2(g)}\]

where ΔfG (NO2) = 52.0 kJ/mol

ΔfG (NO) = 87.0 kJ/mol

ΔfG (O2) = 0 kJ/mol


Predict which of the following reaction will have the appreciable concentration of reactants and products:

  1. \[\ce{Cl2 (g) ⇌ 2Cl (g)}\] Kc = 5 ×10–39
  2. \[\ce{Cl2 (g) + 2NO (g) ⇌ 2NOCl (g)}\] Kc = 3.7 × 108
  3. \[\ce{Cl2 (g) + 2NO2 (g) ⇌ 2NO2Cl (g)}\] Kc = 1.8

The reaction, \[\ce{CO(g) + 3H2(g) ↔ CH4(g) + H2O(g)}\] is at equilibrium at 1300 K in a 1L flask. It also contains 0.30 mol of CO, 0.10 mol of H2 and 0.02 mol of H2O and an unknown amount of CH4 in the flask. Determine the concentration of CH4 in the mixture. The equilibrium constant, Kc for the reaction at the given temperature is 3.90.


For the reaction \[\ce{H2 (g) + I2 (g) ⇌ 2HI (g)}\], the standard free energy is  ∆GΘ > 0. The equilibrium constant (K ) would be ______.


Match standard free energy of the reaction with the corresponding equilibrium constant.

Column I Column II
(i) ∆GΘ > 0 (a) K > 1
(ii) ∆GΘ > 0  (b) K = 1
(iii) ∆GΘ = 0 (c) K = 0
  (d) K < 1

For the reaction,

\[\ce{N2 + O2(g) ⇌ 2NO(g)}\]

the equilibrium constant is K1. The equilibrium constant is K2 for the reaction

\[\ce{2NO(g) + O2(g) ⇌ 2NO2(g)}\]

What is "K" for the reaction:

\[\ce{NO2(g) ⇌ 1/2 N2(g) + O2(g)}\]?


At 1990 K and 1 atm pressure, there are equal numbers of Cl2 molecules and Cl atoms in the reaction mixture. The value of Kp for the reaction Cl2(g) ⇌ 2Cl(g) under the above conditions is x × 10−1. The value of x is ______. (Rounded-off to the nearest integer)


Sulphide ion in alkaline solution reacts with solid sulphur to form polysulphide ions having formula, \[\ce{S^{2-}2}\], \[\ce{S^{2-}3}\], \[\ce{S^{2-}4}\], etc. if K1 = 12 for \[\ce{S + S^{2-} <=> S^{2-}2}\] and K2 = 132 for \[\ce{2S + S^{2-} <=> S^{2-}3}\], K3 = ______ for \[\ce{S + S^{2-}2 <=> S^{2-}3}\].


The equilibrium constant for the reaction is ______ × 1026.

\[\ce{Fe + CuSO4 <=> FeSO4 + Cu}\] at 25°C.

Given `"E"_("Fe"//"Fe"^(2+))^0` = 0.44 V

`"E"_("Cu"//"Cu"^(2+))^0` = - 0.337 V


The value of Kc is 64 at 800 K for the reaction \[\ce{N2(g) + 3H2(g) <=> 2NH3(g)}\].

The value of Kc for the following reaction is:

\[\ce{NH3(g) <=> 1/2N2(g) + 3/2H2(g)}\]


In which one of the following equilibria, KP ≠ Kc?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×