Please select a subject first
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The quantity of charge required to obtain one mole of aluminium from Al2O3 is ______.
Concept: undefined >> undefined
`E_(cell)^Θ` for some half cell reactions are given below. On the basis of these mark the correct answer.
(a) \[\ce{H^{+} (aq) + e^{-} -> 1/2 H_2 (g); E^Θ_{cell} = 0.00V}\]
(b) \[\ce{2H2O (1) -> O2 (g) + 4H^{+} (aq) + 4e^{-}; E^Θ_{cell} = 1.23V}\]
(c) \[\ce{2SO^{2-}_{4} (aq) -> S2O^{2-}_{8} (aq) + 2e^{-}; E^Θ_{cell} = 1.96V}\]
(i) In dilute sulphuric acid solution, hydrogen will be reduced at cathode.
(ii) In concentrated sulphuric acid solution, water will be oxidised at anode.
(iii) In dilute sulphuric acid solution, water will be oxidised at anode.
(iv) In dilute sulphuric acid solution, \[\ce{SO4^{2-}}\] ion will be oxidised to tetrathionate ion at anode.
Concept: undefined >> undefined
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`E_(cell)^Θ` = 1.1V for Daniel cell. Which of the following expressions are correct description of state of equilibrium in this cell?
(i) 1.1 = `K_c`
(ii) `(2.303RT)/(2F) logK_c` = 1.1
(iii) `log K_c = 2.2/0.059`
(iv) `log K_c` = 1.1
Concept: undefined >> undefined
For the given cell, \[\ce{Mg | Mg^{2+} || Cu^{2+} | Cu}\]
(i) \[\ce{Mg}\] is cathode
(ii) \[\ce{Cu}\] is cathode
(iii) The cell reaction is \[\ce{Mg^+ Cu^{2+} -> Mg^{2+} + Cu}\]
(iv) \[\ce{Cu}\] is the oxidising agent
Concept: undefined >> undefined
Can absolute electrode potential of an electrode be measured?
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Depict the galvanic cell in which the cell reaction is \[\ce{Cu + 2Ag^+ -> 2Ag + Cu^{2+}}\]
Concept: undefined >> undefined
What is electrode potential?
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Consider the following diagram in which an electrochemical cell is coupled to an electrolytic cell. What will be the polarity of electrodes ‘A’ and ‘B’ in the electrolytic cell?
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A galvanic cell has electrical potential of 1.1V. If an opposing potential of 1.1V is applied to this cell, what will happen to the cell reaction and current flowing through the cell?
Concept: undefined >> undefined
How will the pH of brine (aq. \[\ce{NaCl}\] solution) be affected when it is electrolysed?
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Consider a cell given below:
\[\ce{Cu | Cu^{2+} || Cl^{-} | Cl_{2},Pt}\]
Write the reactions that occur at anode and cathode
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Match the terms given in Column I with the units given in Column II.
| Column I | Column II |
| (i) Λm | (a) S cm-¹ |
| (ii) ECell | (b) m-¹ |
| (iii) K | (c) S cm2 mol-¹ |
| (iv) G* | (d) V |
Concept: undefined >> undefined
Match the terms given in Column I with the items given in Column II.
| Column I | Column II |
| (i) Λm | (a) intensive property |
| (ii) ECell | (b) depends on number of ions/volume |
| (iii) K | (c) extensive property |
| (iv) ∆rGCell | (d) increases with dilution |
Concept: undefined >> undefined
Match the items of Column I and Column II.
| Column I | Column II |
| (i) K | (a) I × t |
| (ii) Λm | (b) `Λ_m/Λ_m^0` |
| (iii) α | (c) `K/c` |
| (iv) Q | (d) `G^∗/R` |
Concept: undefined >> undefined
Assertion: ECell should have a positive value for the cell to function.
Reason: `"E"_("cathode") < "E"_("anode")`
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Assertion: Mercury cell does not give steady potential.
Reason: In the cell reaction, ions are not involved in solution.
Concept: undefined >> undefined
The term ‘sorption’ stands for ______.
Concept: undefined >> undefined
Which one of the following is not applicable to the phenomenon of adsorption?
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Which of the following is an example of absorption?
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On the basis of data given below predict which of the following gases shows least adsorption on a definite amount of charcoal?
| Gas | CO2 | SO2 | CH1 | H2 |
| Critical temp./K | 304 | 630 | 190 | 33 |
Concept: undefined >> undefined
