Advertisements
Advertisements
प्रश्न
A galvanic cell has electrical potential of 1.1V. If an opposing potential of 1.1V is applied to this cell, what will happen to the cell reaction and current flowing through the cell?
Advertisements
उत्तर
When the opposing potential becomes equal to electrical potential, the cell reaction stops and no current flows through the cell. Thus, there is no chemical reaction.
APPEARS IN
संबंधित प्रश्न
What happens if external potential applied becomes greater than E°cell of electrochemical cell?
Can you store copper sulphate solutions in a zinc pot?
Arrange the following metals in the order in which they displace each other from the solution of their salts.
Al, Cu, Fe, Mg and Zn.
Among Zn and Cu, which would occur more readily in nature as metal and which as an ion?
For the electrochemical cell:
\[\ce{M | M+ || X- | X}\];
\[\ce{E^{\circ}_{{M^{+}/{M}}}}\] = 0.44 V,
\[\ce{E^{\circ}_{X/X^-}}\] = 0.33 V
Which of the following is TRUE for this data?
At 25°C, the emf of the following electrochemical cell.
\[\ce{Ag_{(s)} | Ag^+ (0.01 M) | | Zn^{2+} {(0.1 M)} | Zn_{(s)}}\] will be:
(Given \[\ce{E^0_{cell}}\] = −1.562 V)
In the electrochemical cell: Zn|ZnSO4 (0.01 M)||CuSO4 (1.0 M)|Cu, the emf of this Daniel cell is E1. When the concentration of ZnSO4 is changed to 1.0 M and that CuSO4 changed to 0.01 M, the emf changes to E2. From the above, which one is the relationship between E1 and E2?
Describe the electrolysis of molten NaCl using inert electrodes.
Is it possible to store copper sulphate in an iron vessel for a long time?
Given: \[\ce{E^0_{{Cu^{2+}|{Cu}}}}\] = 0.34 V and \[\ce{E^0_{{Fe^{2+}|{Fe}}}}\] = −0.44 V
A copper electrode is dipped in 0.1 M copper sulphate solution at 25°C. Calculate the electrode potential of copper.
[Given: \[\ce{E^0_{{Cu^{2+}|Cu}}}\] = 0.34 V]
Which of the following statement is correct?
`E_(cell)^Θ` for some half cell reactions are given below. On the basis of these mark the correct answer.
(a) \[\ce{H^{+} (aq) + e^{-} -> 1/2 H_2 (g); E^Θ_{cell} = 0.00V}\]
(b) \[\ce{2H2O (1) -> O2 (g) + 4H^{+} (aq) + 4e^{-}; E^Θ_{cell} = 1.23V}\]
(c) \[\ce{2SO^{2-}_{4} (aq) -> S2O^{2-}_{8} (aq) + 2e^{-}; E^Θ_{cell} = 1.96V}\]
(i) In dilute sulphuric acid solution, hydrogen will be reduced at cathode.
(ii) In concentrated sulphuric acid solution, water will be oxidised at anode.
(iii) In dilute sulphuric acid solution, water will be oxidised at anode.
(iv) In dilute sulphuric acid solution, \[\ce{SO4^{2-}}\] ion will be oxidised to tetrathionate ion at anode.
Depict the galvanic cell in which the cell reaction is \[\ce{Cu + 2Ag^+ -> 2Ag + Cu^{2+}}\]
Match the terms given in Column I with the items given in Column II.
| Column I | Column II |
| (i) Λm | (a) intensive property |
| (ii) ECell | (b) depends on number of ions/volume |
| (iii) K | (c) extensive property |
| (iv) ∆rGCell | (d) increases with dilution |
The electrochemical cell stops working after some time because
Given the data at 25°C
\[\ce{Ag + I- -> AgI + e-}\]; E° = – 0.152 V
\[\ce{Ag -> Ag+ + e-}\]; E° = – 0.800 V
The value of log Ksp for AgI is ______.
Which of the following is incorrect?
The cell constant of a conductivity cell is 0.146 cm-1. What is the conductivity of 0.01 M solution of an electrolyte at 298 K, if the resistance of the cell is 1000 ohm?
