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The quantity of charge required to obtain one mole of aluminium from Al2O3 is ______.

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

`E_(cell)^Θ` for some half cell reactions are given below. On the basis of these mark the correct answer.

(a) \[\ce{H^{+} (aq) + e^{-} -> 1/2 H_2 (g); E^Θ_{cell} = 0.00V}\]

(b) \[\ce{2H2O (1) -> O2 (g) + 4H^{+} (aq) + 4e^{-}; E^Θ_{cell} = 1.23V}\]

(c) \[\ce{2SO^{2-}_{4} (aq) -> S2O^{2-}_{8} (aq) + 2e^{-}; E^Θ_{cell} = 1.96V}\]

(i) In dilute sulphuric acid solution, hydrogen will be reduced at cathode.

(ii) In concentrated sulphuric acid solution, water will be oxidised at anode.

(iii) In dilute sulphuric acid solution, water will be oxidised at anode.

(iv) In dilute sulphuric acid solution, \[\ce{SO4^{2-}}\] ion will be oxidised to tetrathionate ion at anode.

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

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`E_(cell)^Θ` = 1.1V for Daniel cell. Which of the following expressions are correct description of state of equilibrium in this cell?

(i) 1.1 = `K_c`

(ii) `(2.303RT)/(2F) logK_c` = 1.1

(iii) `log K_c = 2.2/0.059`

(iv) `log K_c` = 1.1

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

For the given cell, \[\ce{Mg | Mg^{2+} || Cu^{2+} | Cu}\]

(i) \[\ce{Mg}\] is cathode

(ii) \[\ce{Cu}\] is cathode

(iii) The cell reaction is \[\ce{Mg^+ Cu^{2+} -> Mg^{2+} + Cu}\]

(iv) \[\ce{Cu}\] is the oxidising agent

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Can absolute electrode potential of an electrode be measured?

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Depict the galvanic cell in which the cell reaction is \[\ce{Cu + 2Ag^+ -> 2Ag + Cu^{2+}}\]

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

What is electrode potential?

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Consider the following diagram in which an electrochemical cell is coupled to an electrolytic cell. What will be the polarity of electrodes ‘A’ and ‘B’ in the electrolytic cell?

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

A galvanic cell has electrical potential of 1.1V. If an opposing potential of 1.1V is applied to this cell, what will happen to the cell reaction and current flowing through the cell?

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

How will the pH of brine (aq. \[\ce{NaCl}\] solution) be affected when it is electrolysed?

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Consider a cell given below:
\[\ce{Cu | Cu^{2+} || Cl^{-} | Cl_{2},Pt}\]
Write the reactions that occur at anode and cathode

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Match the terms given in Column I with the units given in Column II.

Column I Column II
(i) Λm (a) S cm-¹
(ii) ECell (b) m-¹
(iii) K (c) S cm2 mol-¹
(iv) G* (d) V
[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Match the terms given in Column I with the items given in Column II.

Column I Column II
(i) Λm (a) intensive property
(ii) ECell (b) depends on number of ions/volume
(iii) K (c) extensive property
(iv) ∆rGCell (d) increases with dilution
[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Match the items of Column I and Column II.

Column I Column II
(i) K (a) I × t
(ii) Λm (b) `Λ_m/Λ_m^0`
(iii) α (c) `K/c`
(iv) Q (d) `G^∗/R`
[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Assertion: ECell should have a positive value for the cell to function.

Reason: `"E"_("cathode") < "E"_("anode")`

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Assertion: Mercury cell does not give steady potential.

Reason: In the cell reaction, ions are not involved in solution.

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

The term ‘sorption’ stands for ______.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
Concept: undefined >> undefined

Which one of the following is not applicable to the phenomenon of adsorption?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
Concept: undefined >> undefined

Which of the following is an example of absorption?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
Concept: undefined >> undefined

On the basis of data given below predict which of the following gases shows least adsorption on a definite amount of charcoal?

Gas CO2 SO2 CH1 H2
Critical temp./K 304 630 190 33
[5] Surface Chemistry
Chapter: [5] Surface Chemistry
Concept: undefined >> undefined
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CBSE Science (English Medium) कक्षा १२ Question Bank Solutions
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