Advertisements
Advertisements
प्रश्न
Can absolute electrode potential of an electrode be measured?
Advertisements
उत्तर
No. It cannot be measured. We can only measure the difference in electrode potential between the two half-cells. We can also measure electrode potential difference concerning a standard electrode.
APPEARS IN
संबंधित प्रश्न
How many electrons flow through a metllic wire if a current of 0·5 A is passed for 2 hours? (Given : 1 F = 96,500 C mol−1)
E°cell for the given redox reaction is 2.71 V
Mg(s) + Cu2+ (0.01 M) → Mg2+ (0.001 M) + Cu(s)
Calculate Ecell for the reaction. Write the direction of flow of current when an external opposite potential applied is
(i) less than 2.71 V and
(ii) greater than 2.71 V
For the electrochemical cell:
\[\ce{M | M+ || X- | X}\];
\[\ce{E^{\circ}_{{M^{+}/{M}}}}\] = 0.44 V,
\[\ce{E^{\circ}_{X/X^-}}\] = 0.33 V
Which of the following is TRUE for this data?
Consider the change in the oxidation state of Bromine corresponding to different emf values as shown in the expression below:
\[\ce{BrO^-_4 ->[1.82 V] BrO^-_3 ->[1.5 V] HBrO ->[1.595 V] Br2 ->[1.0652 V] Br^-}\]
Then the species undergoing disproportionation is:
Define anode
Define cathode
Describe the electrolysis of molten NaCl using inert electrodes.
Describe the construction of Daniel cell. Write the cell reaction.
`E_(cell)^Θ` for some half cell reactions are given below. On the basis of these mark the correct answer.
(a) \[\ce{H^{+} (aq) + e^{-} -> 1/2 H_2 (g); E^Θ_{cell} = 0.00V}\]
(b) \[\ce{2H2O (1) -> O2 (g) + 4H^{+} (aq) + 4e^{-}; E^Θ_{cell} = 1.23V}\]
(c) \[\ce{2SO^{2-}_{4} (aq) -> S2O^{2-}_{8} (aq) + 2e^{-}; E^Θ_{cell} = 1.96V}\]
(i) In dilute sulphuric acid solution, hydrogen will be reduced at cathode.
(ii) In concentrated sulphuric acid solution, water will be oxidised at anode.
(iii) In dilute sulphuric acid solution, water will be oxidised at anode.
(iv) In dilute sulphuric acid solution, \[\ce{SO4^{2-}}\] ion will be oxidised to tetrathionate ion at anode.
Match the terms given in Column I with the items given in Column II.
| Column I | Column II |
| (i) Λm | (a) intensive property |
| (ii) ECell | (b) depends on number of ions/volume |
| (iii) K | (c) extensive property |
| (iv) ∆rGCell | (d) increases with dilution |
Match the items of Column I and Column II.
| Column I | Column II |
| (i) K | (a) I × t |
| (ii) Λm | (b) `Λ_m/Λ_m^0` |
| (iii) α | (c) `K/c` |
| (iv) Q | (d) `G^∗/R` |
Calculate the standard EMF ofa cell which involves the following cell reactions
\[\ce{Zn + 2 Ag+ -> Zn^{2+} + 2 Ag}\]
Given that \[\ce{E^{o}_{Zn/Zn^{2+}}}\] = 0.76 volt and \[\ce{E^{o}_{Ag/Ag^{+}}}\] = – 0.80 volt.
Which of the following statements about galvanic cell is incorrect
Given the data at 25°C
\[\ce{Ag + I- -> AgI + e-}\]; E° = – 0.152 V
\[\ce{Ag -> Ag+ + e-}\]; E° = – 0.800 V
The value of log Ksp for AgI is ______.
On which electrode the oxidation reaction takes place?
What is an electrochemical cell? What does it consist of?
