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Match the items of Column I and Column II. Column I Column II (i) K (a) I × t (ii) Λm (b) ΛmΛm0 (iii) α (c) Kc (iv) Q (d) G⋅R

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प्रश्न

Match the items of Column I and Column II.

Column I Column II
(i) K (a) I × t
(ii) Λm (b) `Λ_m/Λ_m^0`
(iii) α (c) `K/c`
(iv) Q (d) `G^∗/R`
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उत्तर

Column I Column II
(i) K (d) `G^∗/R`
(ii) Λm (c) `K/c`
(iii) α (b) `Λ_m/Λ_m^0`
(iv) Q (a) I × t
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अध्याय 3: Electrochemistry - Exercises [पृष्ठ ४१]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 3 Electrochemistry
Exercises | Q IV. 53. | पृष्ठ ४१

संबंधित प्रश्न

Among Zn and Cu, which would occur more readily in nature as metal and which as an ion?


How many faradays of electricity are required to produce 6 g of Mg from MgCl2?


How many moles of electrons are required for reduction of 2 moles of Zn2+ to Zn?


If one mole electrons is passed through the solutions of CrCl3, AgNO3 and NiSO4, in what ratio Cr, Ag and Ni will be deposited at the electrodes?


Define anode


Describe the construction of Daniel cell. Write the cell reaction.


Can Fe3+ oxidises bromide to bromine under standard conditions?

Given: \[\ce{E^0_{{Fe^{3+}|Fe^{2+}}}}\] = 0.771 V

\[\ce{E^0_{{Br_{2}|Br^-}}}\] = −1.09 V


Two metals M1 and M2 have reduction potential values of −xV and +yV respectively. Which will liberate H2 and H2SO4.


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Given: \[\ce{E^0_{{Mg^{2+}|Mg}}}\] = −2.37 V and \[\ce{E^0_{{Ag^{+}|Ag}}}\] = 0.80 V


Electrode potential for Mg electrode varies according to the equation

`E_(Mg^(2+)  |  Mg) = E_(Mg^(2+)  |  Mg)^Θ - 0.059/2 log  1/([Mg^(2+)])`. The graph of `E_(Mg^(2+)  |  Mg)` vs `log [Mg^(2+)]` is ______.


Which of the following statement is not correct about an inert electrode in a cell?


An electrochemical cell can behave like an electrolytic cell when ______.


Use the data given in below find out the most stable ion in its reduced form.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V

`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V


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(a) \[\ce{H^{+} (aq) + e^{-} -> 1/2 H_2 (g); E^Θ_{cell} = 0.00V}\]

(b) \[\ce{2H2O (1) -> O2 (g) + 4H^{+} (aq) + 4e^{-}; E^Θ_{cell} = 1.23V}\]

(c) \[\ce{2SO^{2-}_{4} (aq) -> S2O^{2-}_{8} (aq) + 2e^{-}; E^Θ_{cell} = 1.96V}\]

(i) In dilute sulphuric acid solution, hydrogen will be reduced at cathode.

(ii) In concentrated sulphuric acid solution, water will be oxidised at anode.

(iii) In dilute sulphuric acid solution, water will be oxidised at anode.

(iv) In dilute sulphuric acid solution, \[\ce{SO4^{2-}}\] ion will be oxidised to tetrathionate ion at anode.


Match the terms given in Column I with the units given in Column II.

Column I Column II
(i) Λm (a) S cm-¹
(ii) ECell (b) m-¹
(iii) K (c) S cm2 mol-¹
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Calculate the standard EMF ofa cell which involves the following cell reactions

\[\ce{Zn + 2 Ag+ -> Zn^{2+} + 2 Ag}\]

Given that \[\ce{E^{o}_{Zn/Zn^{2+}}}\] = 0.76 volt and \[\ce{E^{o}_{Ag/Ag^{+}}}\] = – 0.80 volt.


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Read the passage given below and answer the questions that follow:

Oxidation-reduction reactions are commonly known as redox reactions. They involve transfer of electrons from one species to another. In a spontaneous reaction, energy is released which can be used to do useful work. The reaction is split into two half-reactions. Two different containers are used and a wire is used to drive the electrons from one side to the other and a Voltaic/Galvanic cell is created. It is an electrochemical cell that uses spontaneous redox reactions to generate electricity. A salt bridge also connects to the half-cells. The reading of the voltmeter gives the cell voltage or cell potential or electromotive force. If \[\ce{E^0_{cell}}\] is positive the reaction is spontaneous and if it is negative the reaction is non-spontaneous and is referred to as electrolytic cell. Electrolysis refers to the decomposition of a substance by an electric current. One mole of electric charge when passed through a cell will discharge half a mole of a divalent metal ion such as Cu2+. This was first formulated by Faraday in the form of laws of electrolysis.
The conductance of material is the property of materials due to which a material allows the flow of ions through itself and thus conducts electricity. Conductivity is represented by k and it depends upon nature and concentration of electrolyte, temperature, etc. A more common term molar conductivity of a solution at a given concentration is conductance of the volume of solution containing one mole of electrolyte kept between two electrodes with the unit area of cross-section and distance of unit length. Limiting molar conductivity of weak electrolytes cannot be obtained graphically.

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    OR
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Galvanic cell is a device in which ______.


The cell constant of a conductivity cell is 0.146 cm-1. What is the conductivity of 0.01 M solution of an electrolyte at 298 K, if the resistance of the cell is 1000 ohm?


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