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What is meant by the following term? Give an example of the reaction in the following case.
2, 4-DNP-derivative
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What is meant by the following term? Give an example of the reaction in the following case.
Schiff’s base
Concept: undefined >> undefined
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Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
PhMgBr and then H3O+
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Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
Semicarbazide and weak acid
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Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
Excess ethanol and acid
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Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)
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How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
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Give plausible explanation for the following:
Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
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Give plausible explanation for the following:
There are two −NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.
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Complete the synthesis by giving missing starting material, reagent or product.
\[\ce{C6H5CHO ->[H2NCONHNH2]}\]
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Complete the synthesis by giving missing starting material, reagent or product.

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Give the equations of reactions for the preparation of phenol from cumene.
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Write chemical reaction for the preparation of phenol from chlorobenzene.
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You are given benzene, conc. H2SO4 and NaOH. Write the equations for the preparation of phenol using these reagents.
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Write the equation for the preparation of 1-iodobutane from but-1-ene.
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How will you bring about the following conversion?
Ethane to bromoethene
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How the following conversion can be carried out?
Aniline to chlorobenzene
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What happens when white phosphorus is heated with concentrated NaOH solution in an inert atmosphere of CO2?
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Give reasons CH3NH2 is more basic than C6H5NH2.
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Following data are obtained for reaction :
N2O5 → 2NO2 + 1/2O2
| t/s | 0 | 300 | 600 |
| [N2O5]/mol L–1 | 1.6 × 10-2 | 0.8 × 10–2 | 0.4 × 10–2 |
1) Show that it follows first order reaction.
2) Calculate the half-life.
(Given log 2 = 0.3010, log 4 = 0.6021)
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