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Arrange the following diagrams in correct sequence of steps involved in the mechanism of catalysis, in accordance with modern adsorption theory.

(a)

(b)

(c)

(d)

(e)
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In qualitative analysis when \[\ce{H2S}\] is passed through an aqueous solution of salt acidified with dil. \[\ce{HCl}\], a black precipitate is obtained. On boiling the precipitate with dil. \[\ce{HNO3}\], it forms a solution of blue colour. Addition of excess of aqueous solution of ammonia to this solution gives ______.
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A brown ring is formed in the ring test for \[\ce{NO3^{-}}\] ion. It is due to the formation of ______.
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In the preparation of HNO3, we get NO gas by catalytic oxidation of ammonia. The moles of NO produced by the oxidation of two moles of NH3 will be ______.
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\[\ce{PCl5}\] reacts with finely divided silver on heating and a white silver salt is obtained, which dissolves on adding excess aqueous \[\ce{NH3}\] solution. Write the reactions involved to explain what happens.
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The electronic configuration of \[\ce{Cu(II)}\] is 3d9 whereas that of \[\ce{Cu(I)}\] is 3d10. Which of the following is correct?
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Which of the following complexes formed by \[\ce{Cu^2+}\] ions is most stable?
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When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.
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When 1 mol \[\ce{CrCl3.6H2O}\] is treated with excess of \[\ce{AgNO3}\], 3 mol of \[\ce{AgCl}\] are obtained. The formula of the complex is ______.
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The correct \[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2Cl2]}\] is ______.
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The stabilisation of coordination compounds due to chelation is called the chelate effect. Which of the following is the most stable complex species?
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Which of the following complexes are homoleptic?
(i) \[\ce{[Co(NH3)6]^{3+}}\]
(ii) \[\ce{[Co(NH3)4 Cl2]^{+}}\]
(iii) \[\ce{[Ni(CN)4]^{2-}}\]
(iv) \[\ce{[Ni(NH3)4Cl2]}\]
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Which of the following complexes are heteroleptic?
(i) \[\ce{[Cr(NH3)6]^{3+}}\]
(ii) \[\ce{[Fe(NH3)4]Cl2]^+}\]
(iii) \[\ce{[Mn(CN)6]^{4-}}\]
(iv) \[\ce{[Co(NH3)4]Cl2]}\]
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Identify the correct statements for the behaviour of ethane-1, 2-diamine as a ligand.
(i) It is a neutral ligand.
(ii) It is a didentate ligand.
(iii) It is a chelating ligand.
(iv) It is a unidentate ligand.
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Arrange the following complexes in the increasing order of conductivity of their solution:
[Co(NH3)3Cl3], [Co(NH3)4Cl2]Cl, [Co(NH3)6]Cl3, [Cr(NH3)5Cl]Cl2
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A coordination compound \[\ce{CrCl3.4H2O}\] precipitates silver chloride when treated with silver nitrate. The molar conductance of its solution corresponds to a total of two ions. Write structural formula of the compound and name it.
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A complex of the type \[\ce{[M(AA)2X2]^{n+}}\] is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.
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Match the complex ions given in Column I with the colours given in Column II and assign the correct code:
| Column I (Complex ion) | Column II (Colour) |
| A. \[\ce{[Co(NH3)6]^{3+}}\] | 1. Violet |
| B. \[\ce{[Ti(H2O)6]^{3+}}\] | 2. Green |
| C. \[\ce{[Ni(H2O)6]^{2+}}\] | 3. Pale blue |
| D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] | 4. Yellowish orange |
| 5. Blue |
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Match the coordination compounds given in Column I with the central metal atoms given in Column II and assign the correct code:
| Column I (Coordination Compound) | Column II (Central metal atom) |
| A. Chlorophyll | 1. rhodium |
| B. Blood pigment | 2. cobalt |
| C. Wilkinson catalyst | 3. calcium |
| D. Vitamin B12 | 4. iron |
| 5. magnesium |
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Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code:
| Column I (Compound) | Column II (Oxidation state of Co) |
| A. \[\ce{[Co(NCS)(NH3)5](SO3)}\] | 1. + 4 |
| B. \[\ce{[Co(NH3)4 CL2]SO4}\] | 2. 0 |
| C. \[\ce{Na4[Co(S2O3)3]}\] | 3. + 1 |
| D. \[\ce{[Co2(CO)8]}\] | 4. + 2 |
| 5. + 3 |
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