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Science (English Medium) इयत्ता १२ - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Assertion: The boiling points of alkyl halides decrease in the order:

RI > RBr > RCl > RF

Reason: The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Arrange the following compounds in increasing order of boiling point. Propan-1-ol, butan-1-ol, butan-2-ol, pentan-1-ol

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

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Explain why alcohols and ethers of comparable molecular mass have different boiling points?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Assertion: Boiling points of alcohols and ethers are high.

Reason: They can form intermolecular hydrogen-bonding.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Addition of water to alkynes occurs in acidic medium and in the presence of \[\ce{Hg^{2+}}\] ions as a catalyst. Which of the following products will be formed on addition of water to but-1-yne under these conditions.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Compound \[\begin{array}{cc}
\phantom{.....}\ce{O}\\
\phantom{.....}||\\
\ce{Ph - O - C - Ph}
\end{array}\] can be prepared by the reaction of ______.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

The correct increasing order of basic strength for the following compounds is ______.

(I)


(II)

(III)

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

The most reactive amine towards dilute hydrochloric acid is:

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

The correct decreasing order of basic strength of the following species is ______.

\[\ce{H2O, NH3, OH-, NH^{-}2}\]

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Explain why \[\ce{MeNH2}\] is stronger base than \[\ce{MeOH}\]?

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

In disaccharides, if the reducing groups of monosaccharides i.e. aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?

[10] Biomolecules
Chapter: [10] Biomolecules
Concept: undefined >> undefined

Match the following enzyms given in Column I with the reactions they catalyse given in Column II.

Column I (Enzymes) Column II (Reactions)
(i) Invertase  (a) Decomposition of urea into NH3 and CO2
(ii) Maltase  (b) Conversion of glucose into ethyl alcohol
(iii) Pepsin  (c) Hydrolysis of maltose into glucose
(iv) Urease  (d) Hydrolysis of cane sugar
(v) Zymase  (e) Hydrolysis of proteins into peptides
[10] Biomolecules
Chapter: [10] Biomolecules
Concept: undefined >> undefined

Which of the following statements is not true about low-density polythene?

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Out of chain growth polymerisation and step growth polymerisation, in which type will you place the following.

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

What is the role of benzoyl peroxide in addition polymerisation of alkenes? Explain its mode of action with the help of an example.

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Why should the monomers used in addition polymerisation through free radical pathway be very pure?

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Match the polymer of column I with correct monomer of column II.

Column I Column II
(i) High density polythene (a) Isoprene
(ii) Neoprene (b) Tetrafluoroethene
(iii) Natural rubber (c) Chloroprene
(iv) Teflon (d) Acrylonitrile
(v) Acrilan (e) Ethene
[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Match the polymers given in Column I with their chemical names given in Column II.

Column I Column II
(i) Nylon 6 (a) Polyvinyl chloride
(ii) PVC (b) Polyacrylonitrile
(iii) Acrilan (c) Polycaprolactum
(iv) Natural rubber (d) Low-density polythene
(v) LDP (e) cis-polyisoprene
[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Match the polymers given in Column I with the preferred mode of polymerisation followed by their monomers.

Column I Column II
(i) Nylon-6,6 (a) Free radical polymerisation
(ii) PVC (b) Ziegler-Natta polymerisation or coordination polymerisation
(iii) HDP (c) Anionic polymerisation
  (d) Condensation polymerisation
[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Assertion: Olefinic monomers undergo addition polymerisation.

Reason: Polymerisation of vinyl chloride is initiated by peroxides/ persulphates.

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined
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