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Science (English Medium) इयत्ता १२ - CBSE Important Questions for Chemistry

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Chemistry
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How would you account for the following? 

Zr (Z = 40) and Hf (Z = 72) have almost identical radii.

 

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)

Why do transition elements show variable oxidation states ? In 3d series (Sc to Zn), which elements shows the maximum number of oxidation state and why ?

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)

How would you account the following :

Highest fluoride of Mn is MnF4 whereas the highest oxide is Mn2O7.

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: F-block Elements >> The Actinoids

Complete the following equation :

\[3 {MnO}_4^{2 -} + 4 H^+ \to\]
Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: Some Important Compounds of Transition Elements - Oxides and Oxoanions of Metals

Account for the following : 
Manganese shows maximum number of oxidation states in 3d series. 

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: Some Important Compounds of Transition Elements - Oxides and Oxoanions of Metals

E0 value for  Mn3+ Mn2+ couple is much more positive than that for Cr3-/ Cr2-.

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: Some Important Compounds of Transition Elements - Oxides and Oxoanions of Metals

 Write the chemical equation for the preparation of 4 KMnO from 2. MnO Why does purple colour of acidified permanganate solution decolourise when it oxidises Fe2- to Fe3+

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: Some Important Compounds of Transition Elements - Oxides and Oxoanions of Metals

Account for the following : 
 Ti4+ is colourless whereas V4+  is coloured in an aqueous solutions. 

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)

Why do transition metals exhibit higher enthalpy of atomization? 

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)

Name an element of lanthanoid series which is well knwon to shown +4 oxidation state. Is it a strong oxidising agent or reducing agent? 

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: F-block Elements >> The Lanthanoids

What is lanthanoid contraction? Write the.............

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: F-block Elements >> The Lanthanoids

 Write the ionic equation showing the oxidation of Fe(II) salt by acidified dichromate solutions. 

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: Some Important Compounds of Transition Elements - Oxides and Oxoanions of Metals

Give reasons for the following:
The chemistry of actinoids elements is not so smooth as that of the lanthanoids.

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: F-block Elements >> The Actinoids

How would you account for the following:

There is a greater range of oxidation states among the actinoids than among the lanthanides.

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: F-block Elements >> The Lanthanoids

Account for the following: 

In case of transition elements, ions of the same charge in a given series show progressive decrease in radius with increasing atomic number.

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)

Why are fluorides of transition metals more stable in their higher oxidation state as compared to the lower oxidation state?

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)

It has been observed that first ionization energy of 5 d series of transition elements are higher than that of 3d and 4d series, explain why?

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)

On the basis of the figure given below, answer the following questions:

  1. Why Manganese has lower melting point than Chromium?
  2. Why do transition metals of 3d series have lower melting points as compared to 4d series?
  3. In the third transition series, identify and name the metal with the highest melting point.
Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)

Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Why is Carbon-14 radioactive while Carbon-12 not? (Atomic number of Carbon: 6)

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)

Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Researchers have uncovered the youngest known dinosaur bone, dating around 65 million years ago. How was the age of this fossil estimated?

Appears in 1 question paper
Chapter: [4] d-block and f-block Elements
Concept: General Properties of the Transition Elements (D-block)
< prev  901 to 920 of 1512  next > 
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