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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write a note on free expansion.

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प्रश्न

Write a note on free expansion.

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उत्तर

  1. Free expansions are adiabatic expansions thus there is no exchange of heat between a system and its environment.
  2. Also, there is no work done on the system or by the system. Q = W = 0, and according to the first law of thermodynamics, ΔU = 0.
  3. For example, when a balloon is ruptured suddenly, or a tire is suddenly punctured, the air inside rushes out rapidly but there is no displacement of a piston or any other surface.
  4. A free expansion is different than other thermodynamic processes because it is an uncontrolled change. It is an instantaneous change and the system is not in thermodynamic equilibrium.
  5. A free expansion cannot be plotted on a p-V diagram. Only it's initial and the final state can be plotted.  
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पाठ 4: Thermodynamics - Short Answer II

संबंधित प्रश्‍न

What is a thermodynamic process?


Draw a p-V diagram showing negative work with varying pressure. 


State the assumptions made for thermodynamic processes.


Differentiate between the reversible and irreversible processes.


Explain the cyclic process. 


3 mole of a gas at temperature 400 K expands isothermally from an initial volume of 4 litres to a final volume of 8 litres. Find the work done by the gas. (R = 8.31 J mol-1 K-1)  


Explain the thermodynamics of the isobaric process.  


Explain thermodynamics of the adiabatic process.  


When you exercise in the morning, by considering your body as a thermodynamic system, which of the following is true?


The V-T diagram of an ideal gas which goes through a reversible cycle A→B→C→D is shown below. (Processes D→A and B→C are adiabatic)

The corresponding PV diagram for the process is (all figures are schematic)


In an isochoric process, we have ____________.


Give the equation of state for an adiabatic process.


What are the limitations of the first law of thermodynamics?


Draw the TP diagram (P-x axis, T-y axis), VT(T-x axis, V-y axis) diagram for

  1. Isochoric process
  2. Isothermal process
  3. Isobaric process

In an adiabatic expansion of the air, the volume is increased by 4%, what is the percentage change in pressure? (For air γ = 1.4)


Consider the following cyclic process consist of isotherm, isochoric and isobar which is given in the figure.

Draw the same cyclic process qualitatively in the V-T diagram where T is taken along the x-direction and V is taken along the y-direction. Analyze the nature of heat exchange in each process.


An ideal gas is taken in a cyclic process as shown in the figure. Calculate

  1. work done by the gas
  2. work done on the gas
  3. Net work done in the process


One mole of an ideal gas with `gamma` = 1.4 is adiabatically compressed so that its temperature rises from 27° C to 47° C. The change in the internal energy of the gas is (R = 8.3 J/mol.K) ____________.


In which of the following processes, beat is neither absorbed nor released by a system?


In an isothermal process, the volume of an ideal gas is halved. One can say that ____________.


Assertion: Equal volumes of monatomic and polyatomic gases are adiabatically compressed separately to equal compression ratio `("P"_2/"P"_1)`. Then monatomic gas will have greater final volume.

Reason: Among ideal gases, molecules of a monatomic gas have the smallest number of degrees of freedom.


In the figure shown here, the work done in the process ACBA is ______.


In a certain thermodynamical process, the pressure of a gas depends on its volume as kV3. The work done when the temperature changes from 100°C to 300°C will be ______ nR, where n denotes number of moles of a gas.


When an inflated ballon is suddenly burst, why is the emerging air slightly cooled?


An ideal gas is taken through a cyclic process ABCDA as shown in figure. The net work done by the gas during the cycle is ______.


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