Advertisements
Advertisements
प्रश्न
Why does the rate of a reaction increase with rise in temperature?
Advertisements
उत्तर
At higher temperatures, larger fraction of colliding particles can cross the energy barrier (i.e. the activation energy), which leads to faster rate.
APPEARS IN
संबंधित प्रश्न
Consider the reaction
`3I_((aq))^-) +S_2O_8^(2-)->I_(3(aq))^-) + 2S_2O_4^(2-)`
At particular time t, `(d[SO_4^(2-)])/dt=2.2xx10^(-2)"M/s"`
What are the values of the following at the same time?
a. `-(d[I^-])/dt`
b. `-(d[S_2O_8^(2-)])/dt`
c. `-(d[I_3^-])/dt`
What will be the effect of temperature on rate constant?
The activation energy for the reaction \[\ce{2 HI_{(g)} -> H2_{(g)} + I2_{(g)}}\] is 209.5 kJ mol−1 at 581K. Calculate the fraction of molecules of reactants having energy equal to or greater than activation energy?
The rate constant for the decomposition of hydrocarbons is 2.418 × 10−5 s−1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the value of pre-exponential factor?
The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the energy of activation of the reaction assuming that it does not change with temperature.
Predict the main product of the following reactions:
The chemical reaction in which reactants require high amount of activation energy are generally ____________.
The rate of chemical reaction becomes double for every 10° rise in temperature because of ____________.
Activation energy of a chemical reaction can be determined by ______.
The reaction between \[\ce{H2(g)}\] and \[\ce{O2(g)}\] is highly feasible yet allowing the gases to stand at room temperature in the same vessel does not lead to the formation of water. Explain.
Thermodynamic feasibility of the reaction alone cannot decide the rate of the reaction. Explain with the help of one example.
Why in the redox titration of \[\ce{KMnO4}\] vs oxalic acid, we heat oxalic acid solution before starting the titration?
Total number of vibrational degrees of freedom present in CO2 molecule is
The rate constant for a reaction is 1.5 × 10–7 sec–1 at 50°C. What is the value of activation energy?
The activation energy in a chemical reaction is defined as ______.
The slope of Arrhenius Plot `("In" "k" "v"//"s" 1/"T")` of first-order reaction is −5 × 103 K. The value of Ea of the reaction is. Choose the correct option for your answer. [Given R = 8.314 JK−1mol−1]
Arrhenius equation can be represented graphically as follows:

The (i) intercept and (ii) slope of the graph are:
The equation k = `(6.5 xx 10^12 "s"^(-1))"e"^(- 26000 " K"//"T")` is followed for the decomposition of compound A. The activation energy for the reaction is ______ kJ mol-1. (Nearest integer) (Given: R = 8.314 JK-1 mol-1)
The decomposition of N2O into N2 and O2 in the presence of gaseous argon follows second-order kinetics, with k = (5.0 × 1011 L mol−1 s−1) `"e"^(-(29000 "K")/"T")`. Arrhenius parameters are ______ kJ mol−1.
A schematic plot of ln Keq versus inverse of temperature for a reaction is shown below

The reaction must be:
