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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Which of the following compounds will have the highest melting point and why? (I) (II) (III)

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प्रश्न

Which of the following compounds will have the highest melting point and why?

(I)

(II)

(III)
टीपा लिहा
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उत्तर

 
Compound (II)

Reasons: The molecular structure of compound (II) shows that both the substituents (i.e. \[\ce{CH3}\] and \[\ce{Cl}\] are at para position. The para-isomers have higher melting points as compared to their ortho and meta-isomers. It is due to symmetry of para-isomers that fits in crystal lattice better as compared to ortho-and meta-isomers.

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पाठ 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १४३]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 10 Haloalkanes and Haloarenes
Exercises | Q III. 58. | पृष्ठ १४३

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