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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Out of o-and p-dibromobenzene which one has higher melting point and why?

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प्रश्न

Out of o-and p-dibromobenzene which one has higher melting point and why?

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उत्तर

 p-Dibromobenzenc has higher melting point than its o-isomer.

It is due to symmetry of p-isomer which fits in crystal lattice better than the o-isomer.

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पाठ 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १४२]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 10 Haloalkanes and Haloarenes
Exercises | Q III. 45. | पृष्ठ १४२

संबंधित प्रश्‍न

Arrange the set of compounds in order of increasing boiling points.

Bromomethane, Bromoform, Chloromethane, Dibromomethane.


p-Dichlorobenzene has higher m.p. and lower solubility than those of o- and m-isomers. Discuss.


Define racemic mixture.


Which of the following halide is 2°?


The decreasing order of boiling points of alkyl halides is:


Which of the following possesses the highest melting point?


Mg reacts with RBr best in ____________.


p-dichlorobenzene has a higher melting point than its o- and m-isomers because ____________.


Arrange the following compounds in increasing order of their boiling points.

(a)  \[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
\backslash\phantom{...........}\\
\ce{CH - CH - CH2Br}\\
/\phantom{.............}\\
\ce{CH3}\phantom{..................}
\end{array}\]

(b) \[\ce{CH3CH2CH2CH2Br}\]

(c) \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{H3C - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{Br}
\end{array}\]


Reaction of \[\ce{C6H5CH2Br}\] with aqueous sodium hydroxide follows ______.


Assertion: The boiling points of alkyl halides decrease in the order:

RI > RBr > RCl > RF

Reason: The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.


Arrange the isomeric dichlorobenzene in the increasing order of their boiling point and melting points.


Write the structure of the following organic halogen compound.

4-tert-Butyl-3-iodoheptane


Write the structure of the following organic halogen compound.

4-tert-Butyl-3-iodoheptane


Write the structure of the following organic halogen compound.

4-tert-Butyl-3-iodoheptane


Write the structure of the following organic halogen compound:

4-tert-Butyl-3-iodoheptane


Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

 \[\ce{CH3 C(C2H5)2CH2Br}\]


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