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प्रश्न
Arrange the set of compounds in order of increasing boiling points.
1-Chloropropane, Isopropyl chloride, 1-Chlorobutane.
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उत्तर
Molecules with the same mass have different boiling points based on their size. Branched compounds have a lower boiling point than straight-chain compounds due to their smaller surface area and compact structure. The order of boiling points is:
Isopropyl chloride < 1-Chloropropane < 1-Chlorobutane
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(a) \[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
\backslash\phantom{...........}\\
\ce{CH - CH - CH2Br}\\
/\phantom{.............}\\
\ce{CH3}\phantom{..................}
\end{array}\]
(b) \[\ce{CH3CH2CH2CH2Br}\]
(c) \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{H3C - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{Br}
\end{array}\]
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