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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Mark the correct increasing order of reactivity of the following compounds with HBr/HCl. (a) (b) (c)

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प्रश्न

Mark the correct increasing order of reactivity of the following compounds with HBr/HCl.

(a)
(b)
(c)

पर्याय

  • a < b < c

  • b < a < c

  • b < c < a

  • c < b < a

MCQ
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उत्तर

b < c < a

Explanation:

It is type of nucleophilic substitution reaction followed by SN1 mechanism. SN1 mechanism depends on the stability of carbonation. Presence of electron-withdrawing group will decrease the stability of carbocation.

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पाठ 11: Alcohols, Phenols and Ethers - Multiple Choice Questions (Type - I) [पृष्ठ १५७]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 11 Alcohols, Phenols and Ethers
Multiple Choice Questions (Type - I) | Q 15 | पृष्ठ १५७

संबंधित प्रश्‍न

Give the equation of the following reaction:

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\[\begin{array}{cc}
\phantom{...................................}\ce{Br}\\
\phantom{..................................}|\\
\ce{CH3 - CH - CH - CH3 ->[HBr] CH3 - C - CH2 - CH3}\\
|\phantom{.........}|\phantom{...................................}|\phantom{...........}\\
\ce{CH3}\phantom{...}\ce{OH}\phantom{...............................}\ce{CH3}\phantom{.......}\\
\end{array}\]

Give a mechanism for this reaction.

(Hint: The secondary carbocation formed in step II rearranges to a more

stable tertiary carbocation by a hydride ion shift from 3rd carbon atom.)


Write the mechanism (using curved arrow notation) of the following reaction :


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(i) H2/Pd

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  1. \[\ce{CH3CH2CH(OH)CH3}\]
  2. \[\ce{(C2H5)3COH}\]



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Explain why is OH group in phenols more strongly held as compared to OH group in alcohols.


Explain why nucleophilic substitution reactions are not very common in phenols.


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What is Lucas reagent?


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Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene


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