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प्रश्न
Give two evidences for presence of formyl group in glucose.
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उत्तर
- Glucose gets oxidized to a six-carbon monocarboxylic acid called gluconic acid on reaction with bromine water which is a mild oxidizing agent. Thus, the carbonyl group in glucose is in the form of formyl (–CHO).
- Hemiacetal group of glucopyranose structure is a potential aldehyde (formyl) group. It imparts reducing properties to glucose. Thus, glucose gives positive Tollen’s test or Fehling test.
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संबंधित प्रश्न
Draw a neat diagram for the following:
Haworth formula of glucopyranose.
The glycosidic linkage in maltose is formed between _______________
Draw the structure of α-D glucopyranose.
Write the name of the unit to which glucose unit is linked to from sucrose.
Write chemical reaction for following conversions
glucose into glucoxime
What is the action of the following reagents on glucose?
acetic anhydride
What is the action of the following reagents on glucose?
hydrogen iodide
Write a chemical reaction to convert glucose into glucose cyanohydrin.
Draw the structure of the pyran.
By which of the following process formation of glycosidic bond occurs?
Identify the given structure 'P' and 'Q'.
Which of the following is the basic unit of carbohydrates?
The reserve food material in animals is ____________.
From the following identify the materials that are made up of cellulose.
i. Plant cell wall
ii. Exoskeleton of arthropods
iii. Paper from plant pulp
iv. Cotton fibre
Which is the product obtained, when Br2 water reacts with glucose?
____________ do not give smaller sugar units on hydrolysis.
From the following identify the two types of glucose polymers present in starch.
Identify the CORRECT combination.
Match the columns and select the correct option.
| Column I | Column II | ||
| i. | Starch | a. | Animal storage molecule |
| ii. | Cellulose | b. | Plant storage molecule |
| iii. | Glycogen | c. | Heparin |
| iv. | Heteropolysaccharide | d. | Plant cell wall component |
Raffinose, sucrose and stachyose are respectively ____________.
All these carbohydrates contain \[\ce{1 -> 4β}\] glycosidic linkage, EXCEPT ____________.
\[\ce{CH3 - CH2 - CH2 - Br ->[Na][dry ether] A ->[Cl2] B}\]
Identify the product B in the above reaction.
Which one of the following is Tetrose sugar?
Which of the following statements is NOT true for glyceraldehyde?
Which among the following statements is true for amylose?
Which one of the following sugar does NOT have same empirical fonnula as that of carbohydrate?
How many moles of fructose and galactose respectively are obtained on hydrolysis of 1 mole stachyose?
Identify the number of secondary carbon atoms in glucose.
Which among the following sugars does not reduce Tollen's reagent?
What is the quantity of glucose obtained when 68.4 g of sucrose is hydrolyzed in laboratory under ideal condition?
(Molar mass of sucrose = 342 g mol−1)
Which among the following reagents is used to obtain gluconic acid from glucose?
Identify the product Y in the following reaction.
\[\ce{Maltose ->[Hydrolysis] X ->[dil. HNO3][(excess)] Y}\]
When one mole of lactose is hydrolysed, the hydrolysate contains ____________.
How many optical isomers are possible for a compound having four asymmetric carbon atoms?
What are reducing and non-reducing sugars?
Why carbohydrates are generally optically active?
Is the following sugar, D-sugar or L-sugar?
The molecule of glucose is also called ______.
Which carbon atoms of fructose are bonded together through oxygen forming fructofuranose?
Match the Column I with Column II and choose the correct answer from options below:
| Column I | Column II |
| A. Purine | 1. Glycogen |
| B. Pyrimidine | 2. Cellulose |
| C. Structural polysaccharide | 3. Glucagon |
| D. Storage polysaccharide | 4. Adenine |
| 5. Cytosine |
Corn is immersed in boiling water. It is then cooled, and the solution becomes sweet. It is due to ______.
Consider the following reaction
\[\ce{A <-[Br2 - H2O] Glucose ->[HNO3] B}\]
Here, 'A' and 'B' are respectively.
Why carbohydrates are generally optically active.
Why carbohydrates are generally optically active?
Describe the action of the following reagent on glucose:
Bromine water
Why carbohydrates are generally optically active.
Why are carbohydrates generally optically active?
\[\ce{CH2OH - CO - (CHOH)4 - CH2 OH}\] is an example of ______.
Why carbohydrates are generally optically active?
\[\ce{CH2OH - CO - (CHOH)4 - CH2OH}\] is an example of ______.
