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Define Order of Reaction. How Does Order of a Reaction Differ from Molecularity for a Complex Reaction?

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प्रश्न

Define order of reaction. How does order of a reaction differ from molecularity for a complex reaction? 

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उत्तर

 Order of Reaction :
 Rate = K[A]x [B]y 
 (x + y) = order of that chemical reaction. 
The sum of powers of the concentration of the reactants in the rate law expression is called the order of that chemical reaction.

Order of Reaction Molecularity
Sum of power of the concentration of the reactants in the rate law expression The number of reacting species (atoms, ions or molecules) taking part in an elementing reaction,  which must colloide simultaneously in order to being about a chemical reaction.
Order is an experimental quantity
It can be 0 or fraction.
It cannot be zero or a non- integer
Order is applicable to elementary as well as
complex reaction
For complex reaction, molecularity has no meaning. 
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2018-2019 (March) 56/3/2

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