मराठी

Define Order of Reaction. How Does Order of a Reaction Differ from Molecularity for a Complex Reaction? - Chemistry

Advertisements
Advertisements

प्रश्न

Define order of reaction. How does order of a reaction differ from molecularity for a complex reaction? 

फरक स्पष्ट करा
टीपा लिहा
Advertisements

उत्तर

 Order of Reaction :
 Rate = K[A]x [B]
 (x + y) = order of that chemical reaction. 
The sum of powers of the concentration of the reactants in the rate law expression is called the order of that chemical reaction.

Order of Reaction Molecularity
Sum of power of the concentration of the reactants in the rate law expression The number of reacting species (atoms, ions or molecules) taking part in an elementing reaction,  which must colloide simultaneously in order to being about a chemical reaction.
Order is an experimental quantity
It can be 0 or fraction.
It cannot be zero or a non- integer
Order is applicable to elementary as well as
complex reaction
For complex reaction, molecularity has no meaning. 
shaalaa.com
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
2018-2019 (March) 56/3/2

APPEARS IN

संबंधित प्रश्‍न

The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume.

\[\ce{SO2Cl2_{(g)} -> SO2_{(g)} + Cl2_{(g)}}\]

Experiment Time/s–1 Total pressure/atm
1 0 0.5
2 100 0.6

Calculate the rate of the reaction when total pressure is 0.65 atm.


In a pseudo first order hydrolysis of ester in water, the following results were obtained:

t/s 0 30 60 90
[A]/mol L−1 0.55 0.31 0.17 0.085

Calculate the average rate of reaction between the time interval 30 to 60 seconds.


A first order reaction takes 20 minutes for 25% decomposition. Calculate the time when 75% of the reaction will be completed.

(Given : log = 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021)


First order reaction is 50% complete in 1.26 × 1014s. How much time could it take for 100% completion?


Observe the graph shown in figure and answer the following questions:

  1. What is the order of the reaction?
  2. What is the slope of the curve?
  3. Write the relationship between k and t1/2 (half life period).

The reaction \[\ce{SO2Cl2(g) -> SO2(g) + Cl2(g)}\] is a first-order gas reaction with k = 2.2 × 10−5 sec−1 at 320°C. The percentage of SO2Cl2 is decomposed on heating this gas for 90 min, is ______%.


Radioactive decay follows first-order kinetics. The initial amount of two radioactive elements X and Y is 1 gm each. What will be the ratio of X and Y after two days if their half-lives are 12 hours and 16 hours respectively?


Define first-order reaction.


Slove: \[\ce{2NOBr -> 2NO_{2(g)} + Br_{2(g)}}\]

For the above reaction, the rate law is rate = k[NOBr]2. If the rate of reaction is 6.5 × 10−6 mol L−1 s−1 at 2 × 10−3 mol L−1 concentration of NOBr, calculate the rate constant k for the reaction.


Write the equation for integrated rate law for a first order reaction.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×