Advertisements
Advertisements
प्रश्न
A first order reaction is 50% complete in 25 minutes. Calculate the time for 80% completion of the reaction.
Advertisements
उत्तर
`t_{1//2} = 25 ` minutes ⇒k = `0.693 /{25 "mins"}`
K = `2.303/25 = 2.303/tlog 100/{a_1} `
⇒ `0.693/25 = 2.303/t log 100/20` 80% completion
`t = 2.303/0.693 xx 25 xx 0.6990`
t = 57.3 mins
APPEARS IN
संबंधित प्रश्न
The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume.
\[\ce{SO2Cl2_{(g)} -> SO2_{(g)} + Cl2_{(g)}}\]
| Experiment | Time/s–1 | Total pressure/atm |
| 1 | 0 | 0.5 |
| 2 | 100 | 0.6 |
Calculate the rate of the reaction when total pressure is 0.65 atm.
For the decomposition of azoisopropane to hexane and nitrogen at 543 K, the following data are obtained.
| t (sec) | P(mm of Hg) |
| 0 | 35.0 |
| 360 | 54.0 |
| 720 | 63.0 |
Calculate the rate constant.
A first order reaction takes 20 minutes for 25% decomposition. Calculate the time when 75% of the reaction will be completed.
(Given : log = 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021)
State a condition under which a bimolecular reaction is kinetically first order reaction.
In the first order reaction, half of the reaction is complete in 100 seconds. The time for 99% of the reaction to occurs will be
The reaction X → product
Follow first order of kinetics. In 40 minutes the concentration of 'X' changes from 0.1 m to 0.025. M. The rate of reaction when concentration of X is 0.01 m is.
Observe the graph shown in figure and answer the following questions:

- What is the order of the reaction?
- What is the slope of the curve?
- Write the relationship between k and t1/2 (half life period).
Define first-order reaction.
The rate constant for the reaction:
\[\ce{2N2O_{(s)} ->2N2O4_{(g)}}\] is 4.98 × 10-4 s-1.
The order of the reaction is ______.
Write the unit of rate constant [k] for the first order reaction.
