Advertisements
Advertisements
प्रश्न
A first order reaction is 50% complete in 25 minutes. Calculate the time for 80% completion of the reaction.
Advertisements
उत्तर
`t_{1//2} = 25 ` minutes ⇒k = `0.693 /{25 "mins"}`
K = `2.303/25 = 2.303/tlog 100/{a_1} `
⇒ `0.693/25 = 2.303/t log 100/20` 80% completion
`t = 2.303/0.693 xx 25 xx 0.6990`
t = 57.3 mins
APPEARS IN
संबंधित प्रश्न
Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law with t1/2 = 3 hours. What fraction of the sample of sucrose remains after 8 hours?
Following data are obtained for reaction :
N2O5 → 2NO2 + 1/2O2
| t/s | 0 | 300 | 600 |
| [N2O5]/mol L–1 | 1.6 × 10-2 | 0.8 × 10–2 | 0.4 × 10–2 |
1) Show that it follows first order reaction.
2) Calculate the half-life.
(Given log 2 = 0.3010, log 4 = 0.6021)
Straight line graph for first order reaction is obtained between ____________.
Time required to decompose SO2Cl2 to half of its initial concentration is 60 minutes. If the de-composite is a first order reaction, calculated the rate constant of the reaction-
In a first order reaction the concentration of reactants decreases from 400mol L-1 to 25 mol L-1 in 200 seconds. The rate constant for the reaction is ______.
Observe the graph shown in figure and answer the following questions:

- What is the order of the reaction?
- What is the slope of the curve?
- Write the relationship between k and t1/2 (half life period).
Gaseous cyclobutene isomerizes to butadiene in a first order process which has a 'k' value of 3.3 × 10−4 s−1 at 153°C. The time in minutes it takes for the isomerization to proceed 40% to completion at this temperature is ______. (Rounded-off to the nearest integer)
Slove: \[\ce{2NOBr -> 2NO_{2(g)} + Br_{2(g)}}\]
For the above reaction, the rate law is rate = k[NOBr]2. If the rate of reaction is 6.5 × 10−6 mol L−1 s−1 at 2 × 10−3 mol L−1 concentration of NOBr, calculate the rate constant k for the reaction.
The rate constant for the reaction:
\[\ce{2N2O_{(s)} ->2N2O4_{(g)}}\] is 4.98 × 10-4 s-1.
The order of the reaction is ______.
Write the unit of rate constant [k] for the first order reaction.
