Advertisements
Advertisements
प्रश्न
The slope in the plot of ln[R] vs. time for a first order reaction is ______.
पर्याय
`(+k)/2.303`
– k
`(-k)/2.303`
+ k
Advertisements
उत्तर
The slope in the plot of ln[R] vs. time for a first order reaction is – k.
Explanation:
For the reaction, R `rightarrow` Products
The integrated first order rate equation is
ln [R] = – kt + ln [R0]
Comparing the above equation with a straight line equation y = mx + c
∴ y = ln [R], x = t, slope = – k and intercept = ln [R0]
Thus, the slope for first order reaction is – k.
APPEARS IN
संबंधित प्रश्न
The rate constant for a first order reaction is 60 s−1. How much time will it take to reduce the initial concentration of the reactant to its `1/16`th value?
The time required for 10% completion of a first order reaction at 298 K is equal to that required for its 25% completion at 308 K. If the value of A is 4 × 1010 s−1. Calculate k at 318 K and Ea.
A first order reaction is 50% completed in 1.26 × 1014 s. How much time would it take for 100% completion?
The rate constant of a first order reaction is 6.9 × 10–3s–1. How much time will it take to reduce the initial concentration to its 1/8th value?
First order reaction is 50% complete in 1.26 × 1014s. How much time could it take for 100% completion?
In a first order reaction the concentration of reactants decreases from 400mol L-1 to 25 mol L-1 in 200 seconds. The rate constant for the reaction is ______.
Observe the graph shown in figure and answer the following questions:

- What is the order of the reaction?
- What is the slope of the curve?
- Write the relationship between k and t1/2 (half life period).
The reaction \[\ce{SO2Cl2(g) -> SO2(g) + Cl2(g)}\] is a first-order gas reaction with k = 2.2 × 10−5 sec−1 at 320°C. The percentage of SO2Cl2 is decomposed on heating this gas for 90 min, is ______%.
The slope in the plot of `log ["R"]_0/(["R"])` Vs. time for a first-order reaction is ______.
Write the unit of rate constant [k] for the first order reaction.
