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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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Define Mole fraction.

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Define Molality.

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Define Molarity (M).

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Define Mass percentage.

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Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in aqueous solution. What should be the molarity of such a sample of the acid if the density of the solution is 1.504 g mL−1?

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A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL−1, then what shall be the molarity of the solution?

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How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?

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A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass. Calculate the mass percentage of the resulting solution.

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An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water. Calculate the molality of the solution. If the density of the solution is 1.072 g mL−1, then what shall be the molarity of the solution?

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A sample of drinking water was found to be severely contaminated with chloroform (CHCl3) supposed to be a carcinogen. The level of contamination was 15 ppm (by mass):

  1. express this in percent by mass.
  2. determine the molality of chloroform in the water sample.
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If the density of some lake water is 1.25 g mL−1 and contains 92 g of Na+ ions per kg of water, calculate the molality of Na+ ions in the lake.

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If the solubility product of CuS is 6 × 10−16, calculate the maximum molarity of CuS in aqueous solution.

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Calculate the mass percentage of aspirin (C9H8O4) in acetonitrile (CH3CN) when 6.5 g of C9H8O4 is dissolved in 450 g of CH3CN.

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Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users. Dose of nalorphene generally given is 1.5 mg. Calculate the mass of 1.5 × 10−3 m aqueous solution required for the above dose.

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Given the standard electrode potentials,

K+/K = −2.93 V, Ag+/Ag = 0.80 V,

Hg2+/Hg = 0.79 V

Mg2+/Mg = −2.37 V, Cr3+/Cr = −0.74 V

Arrange these metals in their increasing order of reducing power.

[2] Electrochemistry
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Depict the galvanic cell in which the reaction \[\ce{Zn(s) + 2Ag+(aq) → Zn^{2+}(aq) + 2Ag(s)}\] takes place. Further show:

  1. Which of the electrode is negatively charged?
  2. The carriers of the current in the cell.
  3. Individual reaction at each electrode.
[2] Electrochemistry
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The decomposition of NH3 on platinum surface is zero order reaction. What are the rates of production of N2 and H2 if k = 2.5 × 10−4 mol−1 L s−1?

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:

Experiment A/mol L−1 B/mol L−1 Initial rate/mol L−1 min−1
I 0.1 0.1 2.0 × 10−2
II ______ 0.2 4.0 × 10−2
III 0.4 0.4 ______
IV ______ 0.2 2.0 × 10−2
[3] Chemical Kinetics
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Why is adsorption always exothermic?

[5] Surface Chemistry
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Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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