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Arrange the following:
In increasing order of basic strength:
C6H5NH2, C6H5NHCH3, C6H5CH2NH2
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Arrange the following:
In decreasing order of basic strength in the gas phase:
C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3
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Write a short note on the following:
Carbylamine reaction
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Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
Zinc amalgam and dilute hydrochloric acid
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How will you bring about the following conversion in not more than two steps?
Propanone to Propene
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How will you bring about the following conversion in not more than two steps?
Benzoic acid to m-Nitrobenzyl alcohol
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Complete the synthesis by giving missing starting material, reagent or product.
\[\ce{CH3COCH2COOC2H5 ->[(i) NaBH4][(ii) H+]}\]
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Arrange the set of compounds in order of increasing boiling points.
Bromomethane, Bromoform, Chloromethane, Dibromomethane.
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Arrange the set of compounds in order of increasing boiling points.
1-Chloropropane, Isopropyl chloride, 1-Chlorobutane.
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Explain why alkyl halides, though polar, are immiscible with water?
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p-Dichlorobenzene has higher m.p. and lower solubility than those of o- and m-isomers. Discuss.
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What type of isomerism is shown by the complex [Co(en)3]Cl3
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What type of isomerism is shown by the complex [Co(NH3)6] [Cr(CN)6]?
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What is the effect of adding a catalyst on Activation energy (Ea)
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What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?
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The cell in which the following reaction occurs:
`2Fe^(3+) (aq) + 2I^(-) (aq) ---> 2Fe^(2+) (aq) + I_2 (s)` has `E_"cell"^@` = 0.236 V at 298 K. Calculate the standard Gibbs energy of the cell reaction. (Given : 1 F = 96,500 C mol−1)
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A first-order reaction is 50% completed in 40 minutes at 300 K and in 20 minutes at 320 K. Calculate the activation energy of the reaction. (Given : log 2 = 0·3010, log 4 = 0·6021, R = 8·314 JK–1 mol–1)
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What type of isomerism is exhibited by the complex [Co(NH3)5Cl]SO4?
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Write the structures of the main products of the following reactions:

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Write the structures of the main products of the following reactions:

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