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प्रश्न
Define azeotropes.
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उत्तर
Azeotropes are the binary mixtures of solutions that have the same composition in liquid and vapour phases and that have constant boiling points.
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संबंधित प्रश्न
State Raoult’s law for the solution containing volatile components
Why does a solution containing non-volatile solute have higher boiling point than the pure solvent ?
Calculate the mass of a non-volatile solute (molar mass 40 g mol−1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate:
- molar mass of the solute.
- vapour pressure of water at 298 K.
Define Raoult’s law for the elevation of the boiling point of a solution.
The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows ____________.
Using Raoult’s law explain how the total vapour pressure over the solution is related to mole fraction of components in the following solutions.
\[\ce{CHCl3(l) and CH2Cl2(l)}\]
Using Raoult’s law explain how the total vapour pressure over the solution is related to mole fraction of components in the following solutions.
\[\ce{NaCl(s) and H2O(l)}\]
The correct option for the value of vapour pressure of a solution at 45°C with benzene to octane in a molar ratio of 3 : 2 is
[At 45°C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume Ideal gas]
The vapour pressure of pure liquid X and pure liquid Y at 25°C are 120 mm Hg and 160 mm Hg respectively. If equal moles of X and Y are mixed to form an ideal solution, calculate the vapour pressure of the solution.
