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Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Ionisation enthalpies

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
Concept: undefined >> undefined

Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Atomic sizes

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
Concept: undefined >> undefined

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Give an example of chelate effect.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

Draw the structure of the following derivative.

Acetaldehydedimethylacetal

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write the structure of the following compound.

Di-sec.butylketone

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Draw the structure of the following derivative.

The ethylene ketal of hexan-3-one.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write the structure of the compound whose IUPAC name is as follows:

4-Chloro-3-ethylbutan-1-ol

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Write the formula of Tetraminodichloroplatinum (IV) chloridex.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

Sucrose decomposes in acid solution to give glucose and fructose according to the first order rate law. The half life of the reaction is 3 hours. Calculate fraction of sucrose which will remain after 8 hours.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

How will you convert: Propene to Propan-2-ol?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Calculate the e.m.f. of the following cell at 298 K:

Fe(s) | Fe2+ (0.001 M) | | H+ (0.01 M) | H2(g) (1 bar) | Pt(s)

Given that \[\ce{E^0_{cell}}\] = 0.44 V

[log 2 = 0.3010, log 3 = 0.4771, log 10 = 1]

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

For a first order reaction, show that time required for 99% completion is twice the time required for the completion of 90% of reaction.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

 A first order reaction takes 40 minutes for 30% decomposition. Calculate t1/2 for this reaction. (Given log 1.428 = 0.1548)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Write the fomulae of the following compounds

Sodium hexanitrito- N - cobaltate (III)

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

Write the chemical equation involved in the following reaction:

Hoffmann-bromamide degradation reaction

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Write the structures of A and B in the following reactions:

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Complete the following equations:

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
Concept: undefined >> undefined

Complete the following equations: Cr2O72- + 14H+ + 6I →

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
Concept: undefined >> undefined

Using IUPAC norms, write the formula for the following: 

Potassium tetracyanidonickelate(II)

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

Name the reagents used in the following reactions:

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined
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