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On the basis of crystal field theory, write the electronic configuration for d4 with a strong field ligand for which Δ0 > P.
Concept: Bonding in Coordination Compounds >> Crystal Field Theory (CFT)
How do you convert the following:
Ethanol to propanenitrile
Concept: Reactions of Haloalkanes - Nucleophilic Substitution Reactions
Given reasons: C–Cl bond length in chlorobenzene is shorter than C–Cl bond length in CH3–Cl.
Concept: Reactions of Haloalkanes - Nucleophilic Substitution Reactions
How is ‘cast iron’ different from ‘pig iron’?
Concept: Application of Thermodynamic Principles of Metallurgy
Write the structure of the major product in each of the following reaction :
Concept: Reactions of Haloalkanes - Nucleophilic Substitution Reactions
What is the significance of leaching in the extraction of aluminium?
Concept: Types of Separation or Concentration of an Ore >> Leaching
In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction?
Concept: Reactions of Haloalkanes - Nucleophilic Substitution Reactions
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane
Concept: Reactions of Haloalkanes - Nucleophilic Substitution Reactions
Out of PbS and PbCO3 (ores of lead), which one is concentrated by froth floatation process preferably?
Concept: Refining of Crude Metals
Given reasons: SN1 reactions are accompanied by racemization in optically active alkyl halides.
Concept: Reactions of Haloalkanes - Nucleophilic Substitution Reactions
Account for the following :
Iron on reaction with HCl forms FeCl2 nd not FeCl3.
Concept: Uses of Aluminium, Copper, Zinc and Iron
What happens when Silver is leached with NaCN in the presence of air?
Concept: Refining of Crude Metals
Out of (CH3)3 C-Br and (CH3)3 C-I, which one is more reactive towards SN1 and why?
Concept: Reactions of Haloarenes - Nucleophilic Substitution
ICl is more reactive than I2.
Concept: Group 17 Elements - The Halogen Family >> Interhalogen Compounds
Write the IUPAC name of the given compound:
Concept: Nomenclature of Alcohols, Phenols and Ethers
Write the structures of the following molecule:
H2SO3
Concept: Group 16 Elements - The Oxygen Family >> Oxoacids of Sulphur
Give reasons for the following : H2Te is the strongest reducing agent amongst all the hydrides of Group 16 elements.
Concept: Group 16 Elements - The Oxygen Family
Write the structures of the main products when acetone (CH3 − CO − CH3) reacts with the following reagents :
CH3MgBr and then H3O+
Concept: Methods of Preparation of Alcohols
Draw the structures of the following:
(1) HClO4
(2) H3PO3
Concept: Group 17 Elements - The Halogen Family >> Oxoacids of Halogens
Complete the following equation:
\[\ce{XeF2 + H2O ->}\]
Concept: Group 18 Elements - The Noble gas Family
