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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Why does the rate of any reaction generally decreases during the course of the reaction?

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प्रश्न

Why does the rate of any reaction generally decreases during the course of the reaction?

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उत्तर

The rate of a reaction depends on the concentration of reactants. As the reaction progresses, the concentration of reactants decreases because the reactants start getting converted to products. Hence the rate decreases.

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अध्याय 4: Chemical Kinetics - Exercises [पृष्ठ ५६]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 4 Chemical Kinetics
Exercises | Q III. 47. | पृष्ठ ५६

संबंधित प्रश्न

For a reaction : 

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.


For a chemical reaction R → P, the variation in the concentration (R) vs. time (t) plot is given as:

(i) Predict the order of the reaction.

(ii) What is the slope of the curve?

(iii) Write the unit of rate constant for this reaction.


A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is doubled?


Rate of reaction for the combustion of propane is equal to:

\[\ce{C3H8_{(g)} + 5O2_{(g)} -> 3CO2_{(g)} + 4H2O_{(g)}}\]


The value of rate constant of a pseudo first order reaction ______.


In any unimolecular reaction:

(i) only one reacting species is involved in the rate determining step.

(ii) the order and the molecularity of slowest step are equal to one.

(iii) the molecularity of the reaction is one and order is zero.

(iv) both molecularity and order of the reaction are one.


For a complex reaction:

(i) order of overall reaction is same as molecularity of the slowest step.

(ii) order of overall reaction is less than the molecularity of the slowest step.

(iii) order of overall reaction is greater than molecularity of the slowest step.

(iv) molecularity of the slowest step is never zero or non interger.


Why is the probability of reaction with molecularity higher than three very rare?


Why molecularity is applicable only for elementary reactions and order is applicable for elementary as well as complex reactions?


Assertion: Order and molecularity are same.

Reason: Order is determined experimentally and molecularity is the sum of the stoichiometric coefficient of rate determining elementary step.


A catalyst in a reaction changes which of the following?


The role of a catalyst is to change


For a reaction \[\ce{Cl2l(g) + 2No(g) -> 2NaCl(g)}\] the rate law is expressed as rate= K[Cl2] [No]2 what is the order of the reaction?


For reaction 2A + B → BC + D which of the following does not Express the reaction rates


The half-life period of a. substance in a certain enzyme catalysed reaction is 138 s. The time required for the concentration of the substance to fall from 1.28 mol–1 to 0.04 mg L–1 is


Read the following passage and answer the questions that follow:

The rate of reaction is concerned with decrease in the concentration of reactants or increase in the concentration of products per unit of time. It can be expressed as instantaneous rate at a particular instant of time and average rate over a large interval of time. A number of factors such as temperature, concentration of reactants, catalyst affect the rate of reaction. Mathematical representation of rate of a reaction is given by rate law:

Rate = k[A]x [B]y

x and y indicate how sensitive the rate is to change in concentration of A and B. Sum of x + y gives the overall order of a reaction.
When a sequence of elementary reactions gives us the products, the reaction is called complex reaction. Molecularity and order of an elementary reaction are same. Zero-order reactions are relatively uncommon but they occur under special conditions. All natural and artificial radioactive decay of unstable nuclei takes place by first-order kinetics.

  1. What is the effect of temperature on the rate constant of a reason?    [1]
  2. For a reaction \[\ce{A + B → Product}\], the rate law is given by, Rate = k[A]2 [B]1/2. What is the order of the reaction?    [1]
  3. How order and molecularity are different for complex reactions?    [1]
  4. A first-order reaction has a rate constant 2 × 10–3 s–1. How long will 6 g of this reactant take to reduce to 2 g?    [2]
    OR
    The half-life for radioactive decay of 14C is 6930 years. An archaeological artifact containing wood had only 75% of the 14C found in a living tree. Find the age of the sample.
    [log 4 = 0.6021, log 3 = 0.4771, log 2 = 0.3010, log 10 = 1]    [2]

The following data was obtained for chemical reaction given below at 975 K.

\[\ce{2NO(g) + 2H2(g) -> N2(g) + 2H2O(g)}\]

  [NO] [H2] Rate
  Mol L-1 Mol L-1 Mol L-1 s-1
(1) 8 × 10-5 8 × 10-5 7 × 10-9
(2) 24 × 10-5 8 × 10-5 2.1 × 10-8
(3) 24 × 10-5 32 × 10-5 8.4 × 10-8

The order of the reaction with respect to NO is ______. (Integer answer)


For a chemical reaction starting with some initial concentration of reactant At as a function of time (t) is given by the equation,

`1/("A"_"t"^4) = 2 + 1.5 xx 10^-3` t

The rate of disappearance of [A] is ____ × 10-2 M/sec when [A] = 2 M.

[Given: [At] in M and t in sec.]
[Express your answer in terms of 10-2 M /s]
[Round off your answer if required]


A flask contains a mixture of compounds A and B. Both compounds decompose by first-order kinetics. The half-lives for A and B are 300 s and 180 s, respectively. If the concentrations of A and B are equal initially, the time required for the concentration of A to be four times that of B (in s) is ______. (Use ln 2 = 0.693)


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