Advertisements
Advertisements
प्रश्न
Using valence bond theory, explain the following in relation to the complexes given below:
\[\ce{[Mn(CN)6]^{3-}}\]
(i) Type of hybridisation.
(ii) Inner or outer orbital complex.
(iii) Magnetic behaviour.
(iv) Spin only magnetic moment value.
Advertisements
उत्तर
\[\ce{[Mn(CN)6]^{3-}}\]:
(i) Hybridisation – d2sp3
(ii) Inner orbital complex
(iii) Paramagnetic
(iv) Magnetic moment = `sqrt(2(2 + 2))` = 2.87 B.M
APPEARS IN
संबंधित प्रश्न
Explain on the basis of valence bond theory that [Ni(CN)4]2− ion with square planar structure is diamagnetic and the [NiCl4]2− ion with tetrahedral geometry is paramagnetic.
Predict the number of unpaired electrons in the square planar [Pt(CN)4]2− ion.
[Cr(NH3)6]3+ is paramagnetic while [Ni(CN)4]2− is diamagnetic. Explain why?
Explain the geometry of `[Co(NH_3)_6]^(3+)` on the basis of hybridisation. (Z of Co = 27)
[NiCl4]2- is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why? (Atomic no. Ni = 28)
The type of hybridization involved in Octahedral complexes is ______.
If orbital quantum number (l) has values 0, 1, 2 and 3, deduce the corresponding value of principal quantum number, n.
Which of the statement given below is incorrect about H2O2?
Which of the following methods is used for measuring bond length?
What is the no. of possible isomers for the octahedral complex [Co(NH3)2(C2O4)2]?
Using Valence bond theory, explain the following in relation to the paramagnetic complex [Mn(CN)6]3−
- type of hybridization
- magnetic moment value
- type of complex – inner, outer orbital complex
The magnetic moment of [NiCl4]2− is ______.
[Atomic number: Ni = 28]
[Ni(CO)4] has tetrahedral geometry while [Ni(CN)4]2− has square planar, yet both exhibit diamagnetism. Explain.
[Atomic number: Ni = 28]
During chemistry class, a teacher wrote \[\ce{[Ni(CN)4]^2-}\] as a coordination complex ion on the board. The students were asked to find out the magnetic behaviour and shape of the complex. Pari, a student, wrote the answer paramagnetic and tetrahedral whereas another student Suhail wrote diamagnetic and square planer.
Evaluate Pari’s and Suhail’s responses.
The geometry and magnetic behaviour of the complex [Ni(CO)4] are ______.
Which of the following are paramagnetic?
- [NiCl4]2−
- Ni(CO)4
- [Ni(CN)4]2−
- [Ni(H2O)6]2+
- Ni(PPh3)4
Choose the correct answer from the options given below:
Given below are two statements:
Statement I: Both [Co(NH3)6]3+ and [CoF6]3− complexes are octahedral but differ in their magnetic behavior.
Statement II: [Co(NH3)6]3+ is diamagnetic whereas [CoF6]3− is paramagnetic.
In the light of the above statements, Choose the correct answer form the options given below:
