हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Using valence bond theory, explain the following in relation to the complexes given below: [Cr(HX2O)X6]X3+ (i) Type of hybridisation. (ii) Inner or outer orbital complex. (iii) Magnetic behaviour - Chemistry

Advertisements
Advertisements

प्रश्न

Using valence bond theory, explain the following in relation to the complexes given below:

\[\ce{[Cr(H2O)6]^{3+}}\]

(i) Type of hybridisation.
(ii) Inner or outer orbital complex.
(iii) Magnetic behaviour.
(iv) Spin only magnetic moment value.

दीर्घउत्तर
Advertisements

उत्तर

\[\ce{[Cr(H2O)6]^{3+}}\]:

(i) Hybridisation – d2sp3

(ii) Inner orbital complex

(iii) Paramagnetic

(iv) Magnetic moment = `sqrt(3(3 + 2))` = 3.87 B.M

shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 9: Coordination Compounds - Exercises [पृष्ठ १२७]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 9 Coordination Compounds
Exercises | Q VI. 47. | पृष्ठ १२७

संबंधित प्रश्न

On the basis of valence bond theory explain the nature of bonding in [CoF6]3 ion.

 


[NiCl4]2− is paramagnetic, while [Ni(CO)4] is diamagnetic, though both are tetrahedral. Why? (Atomic number of Ni = 28)


Discuss the nature of bonding in the following coordination entity on the basis of valence bond theory:

[Fe(CN)6]4−


[Cr(NH3)6]3+ is paramagnetic while [Ni(CN)4]2− is diamagnetic. Explain why?


Discuss the nature of bonding in the following coordination entity on the basis of valence bond theory:

[Co(C2O4)3]3−


Write the hybridisation and number of unpaired electrons in the complex `[CoF_6]^(3-)`. (Atomic No. of Co = 27)


Using valence bond theory, explain the following in relation to the complexes given below:

\[\ce{[Co(NH3)6]^{3+}}\]

(i) Type of hybridisation.
(ii) Inner or outer orbital complex.
(iii) Magnetic behaviour.
(iv) Spin only magnetic moment value.


Write the hybridization and shape of the following complexes:

[Ni(CN)4]2−


If orbital quantum number (l) has values 0, 1, 2 and 3, deduce the corresponding value of principal quantum number, n.


Which of the statement given below is incorrect about H2O2?


Which of the following has square planar structures?


What is the no. of possible isomers for the octahedral complex [Co(NH3)2(C2O4)2]?


Using Valence bond theory, explain the following in relation to the paramagnetic complex [Mn(CN)6]3− 

  1. type of hybridization
  2. magnetic moment value
  3. type of complex – inner, outer orbital complex

According to the valence bond theory, the hybridization of central metal atom is dsp2 for which one of the following compounds?


The magnetic moment of [NiCl4]2− is ______.

[Atomic number: Ni = 28]


During chemistry class, a teacher wrote \[\ce{[Ni(CN)4]^2-}\] as a coordination complex ion on the board. The students were asked to find out the magnetic behaviour and shape of the complex. Pari, a student, wrote the answer paramagnetic and tetrahedral whereas another student Suhail wrote diamagnetic and square planer.

Evaluate Pari’s and Suhail’s responses.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×