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प्रश्न
In defining the ideal gas temperature scale, it is assumed that the pressure of the gas at constant volume is proportional to the temperature T. How can we verify whether this is true or not? Do we have to apply the kinetic theory of gases? Do we have to depend on experimental result that the pressure is proportional to temperature?
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उत्तर
The ideal gas thermometer is based on the ideal gas equation, PV=nRT, where P is pressure of the gas at constant volume V with n number of moles at temperature T. Therefore, P = constant × T. According to this relation, if the volume of the gas used is constant, the pressure will be directly proportional to the temperature of the gas. We need not use kinetic theory of gases or any experimental results.
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संबंधित प्रश्न
The triple points of neon and carbon dioxide are 24.57 K and 216.55 K respectively. Express these temperatures on the Celsius and Fahrenheit scales.
Two absolute scales A and B have triple points of water defined to be 200 A and 350 B. What is the relation between TA and TB?
Answer the following:
The triple-point of water is a standard fixed point in modern thermometry. Why? What is wrong in taking the melting point of ice and the boiling point of water as standard fixed points (as was originally done in the Celsius scale)?
Two ideal gas thermometers Aand Buse oxygen and hydrogen respectively. The following observations are made:
| Temperature | Pressure thermometer A | Pressure thermometer B |
| Triple-point of water | 1.250 × 105 Pa | 0.200 × 105 Pa |
| Normal melting point of sulphur | 1.797 × 105 Pa | 0.287 × 105 Pa |
(a) What is the absolute temperature of the normal melting point of sulphur as read by thermometers Aand B?
(b) What do you think is the reason behind the slight difference in answers of thermometers Aand B? (The thermometers are not faulty). What further procedure is needed in the experiment to reduce the discrepancy between the two readings?
A brass wire 1.8 m long at 27 °C is held taut with little tension between two rigid supports. If the wire is cooled to a temperature of –39 °C, what is the tension developed in the wire, if its diameter is 2.0 mm? Co-efficient of linear expansion of brass = 2.0 × 10–5 K–1; Young’s modulus of brass = 0.91 × 1011 Pa.
Consider the following statements.
(A) The coefficient of linear expansion has dimension K–1.
(B) The coefficient of volume expansion has dimension K–1.
The steam point and the ice point of a mercury thermometer are marked as 80° and 20°. What will be the temperature on a centigrade mercury scale when this thermometer reads 32°?
The pressure measured by a constant volume gas thermometer is 40 kPa at the triple point of water. What will be the pressure measured at the boiling point of water (100°C)?
The pressure of the gas in a constant volume gas thermometer is 70 kPa at the ice point. Find the pressure at the steam point.
In a Callender's compensated constant pressure air thermometer, the volume of the bulb is 1800 cc. When the bulb is kept immersed in a vessel, 200 cc of mercury has to be poured out. Calculate the temperature of the vessel.
A piece of iron of mass 100 g is kept inside a furnace for a long time and then put in a calorimeter of water equivalent 10 g containing 240 g of water at 20°C. The mixture attains and equilibrium temperature of 60°C. Find the temperature of the furnace. Specific heat capacity of iron = 470 J kg−1 °C−1.
The temperatures of equal masses of three different liquids A, B and C are 12°C, 19°C and 28°C respectively. The temperature when A and B are mixed is 16°C, and when B and C are mixed, it is 23°C. What will be the temperature when A and C are mixed?
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An aluminium can of cylindrical shape contains 500 cm3 of water. The area of the inner cross section of the can is 125 cm2. All measurements refer to 10°C.
Find the rise in the water level if the temperature increases to 80°C. The coefficient of linear expansion of aluminium is 23 × 10–6 °C–1 and the average coefficient of the volume expansion of water is 3.2 × 10–4 °C–1.
A glass vessel measures exactly 10 cm × 10 cm × 10 cm at 0°C. It is filled completely with mercury at this temperature. When the temperature is raised to 10°C, 1.6 cm3 of mercury overflows. Calculate the coefficient of volume expansion of mercury. Coefficient of linear expansion of glass = 6.5 × 10–1 °C–1.
A steel rod is rigidly clamped at its two ends. The rod is under zero tension at 20°C. If the temperature rises to 100°C, what force will the rod exert on one of the clamps? Area of cross-section of the rod is 2.00 mm2. Coefficient of linear expansion of steel is 12.0 × 10–6 °C–1 and Young's modulus of steel is 2.00 × 1011 Nm–2.
A metal block of density 600 kg m−3 and mass 1.2 kg is suspended through a spring of spring constant 200 N m−1. The spring-block system is dipped in water kept in a vessel. The water has a mass of 260 g and the bloc is at a height 40 cm above the bottom of the vessel. If the support of the spring is broken, what will be the rise in the temperature of the water. Specific heat capacity of the block is 250 J kg−3 K−1 and that of water is 4200 J kg−1 K−1. Heat capacities of the vessel and the spring are negligible.
A torsional pendulum consists of a solid disc connected to a thin wire (α = 2.4 × 10–5°C–1) at its centre. Find the percentage change in the time period between peak winter (5°C) and peak summer (45°C).
Answer the following question.
How a thermometer is calibrated?
If the temperature on the Fahrenheit scale is 140 °F, then the same temperature on the Kelvin scale will be:
Calculate the temperature which has same numeral value on celsius and Fahrenheit scale.
The Zeroth Law of Thermodynamics is the basis for which of the following?
At what temperature do the Celsius and Fahrenheit scales show the same reading?
A wall that allows free exchange of heat between two systems is called ______.
Convert 37 °C (normal body temperature) to Kelvin.
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A mercury thermometer is placed under a patient's tongue. Which sequence correctly describes what happens before a reading is taken?
A platinum wire is used as the thermometric substance in a resistance thermometer. What is the thermometric property being utilised here?
A mercury thermometer has a column length of 20 mm at the ice point and 170 mm at the steam point. If the column length is 65 mm, what is the temperature?
Which of the following is NOT a characteristic of a good thermometer?
