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प्रश्न
In defining the ideal gas temperature scale, it is assumed that the pressure of the gas at constant volume is proportional to the temperature T. How can we verify whether this is true or not? Do we have to apply the kinetic theory of gases? Do we have to depend on experimental result that the pressure is proportional to temperature?
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उत्तर
The ideal gas thermometer is based on the ideal gas equation, PV=nRT, where P is pressure of the gas at constant volume V with n number of moles at temperature T. Therefore, P = constant × T. According to this relation, if the volume of the gas used is constant, the pressure will be directly proportional to the temperature of the gas. We need not use kinetic theory of gases or any experimental results.
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संबंधित प्रश्न
The triple points of neon and carbon dioxide are 24.57 K and 216.55 K respectively. Express these temperatures on the Celsius and Fahrenheit scales.
Two absolute scales A and B have triple points of water defined to be 200 A and 350 B. What is the relation between TA and TB?
The electrical resistance in ohms of a certain thermometer varies with temperature according to the approximate law:
R = Ro [1 + α (T – To)]
The resistance is 101.6 Ω at the triple-point of water 273.16 K, and 165.5 Ω at the normal melting point of lead (600.5 K). What is the temperature when the resistance is 123.4 Ω?
Answer the following:
The triple-point of water is a standard fixed point in modern thermometry. Why? What is wrong in taking the melting point of ice and the boiling point of water as standard fixed points (as was originally done in the Celsius scale)?
Two ideal gas thermometers Aand Buse oxygen and hydrogen respectively. The following observations are made:
| Temperature | Pressure thermometer A | Pressure thermometer B |
| Triple-point of water | 1.250 × 105 Pa | 0.200 × 105 Pa |
| Normal melting point of sulphur | 1.797 × 105 Pa | 0.287 × 105 Pa |
(a) What is the absolute temperature of the normal melting point of sulphur as read by thermometers Aand B?
(b) What do you think is the reason behind the slight difference in answers of thermometers Aand B? (The thermometers are not faulty). What further procedure is needed in the experiment to reduce the discrepancy between the two readings?
A brass wire 1.8 m long at 27 °C is held taut with little tension between two rigid supports. If the wire is cooled to a temperature of –39 °C, what is the tension developed in the wire, if its diameter is 2.0 mm? Co-efficient of linear expansion of brass = 2.0 × 10–5 K–1; Young’s modulus of brass = 0.91 × 1011 Pa.
In which of the following pairs of temperature scales, the size of a degree is identical?
(a) Mercury scale and ideal gas scale
(b) Celsius scale and mercury scale
(c) Celsius scale and ideal gas scale
(d) Ideal gas scale and absolute scale
Which of the following pairs represent units of the same physical quantity?
The pressure measured by a constant volume gas thermometer is 40 kPa at the triple point of water. What will be the pressure measured at the boiling point of water (100°C)?
The pressures of the gas in a constant volume gas thermometer are 80 cm, 90 cm and 100 cm of mercury at the ice point, the steam point and in a heated wax bath, respectively. Find the temperature of the wax bath.
In a Callender's compensated constant pressure air thermometer, the volume of the bulb is 1800 cc. When the bulb is kept immersed in a vessel, 200 cc of mercury has to be poured out. Calculate the temperature of the vessel.
Four 2 cm × 2 cm × 2 cm cubes of ice are taken out from a refrigerator and are put in 200 ml of a drink at 10°C. (a) Find the temperature of the drink when thermal equilibrium is attained in it. (b) If the ice cubes do not melt completely, find the amount melted. Assume that no heat is lost to the outside of the drink and that the container has negligible heat capacity. Density of ice = 900 kg m−3, density of the drink = 1000 kg m−3, specific heat capacity of the drink = 4200 J kg−1 K−1, latent heat of fusion of ice = 3.4 × 105 J kg−1.
A metre scale made of steel reads accurately at 20°C. In a sensitive experiment, distances accurate up to 0.055 mm in 1 m are required. Find the range of temperature in which the experiment can be performed with this metre scale. Coefficient of linear expansion of steel = 11 × 10–6 °C–1.
A glass vessel measures exactly 10 cm × 10 cm × 10 cm at 0°C. It is filled completely with mercury at this temperature. When the temperature is raised to 10°C, 1.6 cm3 of mercury overflows. Calculate the coefficient of volume expansion of mercury. Coefficient of linear expansion of glass = 6.5 × 10–1 °C–1.
A cube of iron (density = 8000 kg m−3, specific heat capacity = 470 J kg−1 K−1) is heated to a high temperature and is placed on a large block of ice at 0°C. The cube melts the ice below it, displaces the water and sinks. In the final equilibrium position, its upper surface just goes inside the ice. Calculate the initial temperature of the cube. Neglect any loss of heat outside the ice and the cube. The density of ice = 900 kg m−3 and the latent heat of fusion of ice = 3.36 × 105 J kg−1.
A steel rod is rigidly clamped at its two ends. The rod is under zero tension at 20°C. If the temperature rises to 100°C, what force will the rod exert on one of the clamps? Area of cross-section of the rod is 2.00 mm2. Coefficient of linear expansion of steel is 12.0 × 10–6 °C–1 and Young's modulus of steel is 2.00 × 1011 Nm–2.
A ball is dropped on a floor from a height of 2.0 m. After the collision it rises up to a height of 1.5 m. Assume that 40% of the mechanical energy lost goes as thermal energy into the ball. Calculate the rise in the temperature of the ball in the collision. Heat capacity of the ball is 800 J K−1.
A metal block of density 600 kg m−3 and mass 1.2 kg is suspended through a spring of spring constant 200 N m−1. The spring-block system is dipped in water kept in a vessel. The water has a mass of 260 g and the bloc is at a height 40 cm above the bottom of the vessel. If the support of the spring is broken, what will be the rise in the temperature of the water. Specific heat capacity of the block is 250 J kg−3 K−1 and that of water is 4200 J kg−1 K−1. Heat capacities of the vessel and the spring are negligible.
A circular disc made of iron is rotated about its axis at a constant velocity ω. Calculate the percentage change in the linear speed of a particle of the rim as the disc is slowly heated from 20°C to 50°C, keeping the angular velocity constant. Coefficient of linear expansion of iron = 1.2 × 10–5 °C–1.
Answer the following question.
How a thermometer is calibrated?
Solve the following problem.
In a random temperature scale X, water boils at 200 °X and freezes at 20 °X. Find the boiling point of a liquid in this scale if it boils at 62 °C.
The graph between two temperature scales A and B is shown in figure. Between upper fixed point and lower fixed point there are 150 equal division on scale A and 100 on scale B. The relationship for conversion between the two scales is given by ______.
At what temperature do the Celsius and Fahrenheit scales show the same reading?
Which thermometer is considered the most accurate?
Which of the following correctly describes an adiabatic wall?
A platinum wire is used as the thermometric substance in a resistance thermometer. What is the thermometric property being utilised here?
Which of the following is NOT a characteristic of a good thermometer?
