Advertisements
Advertisements
प्रश्न
Two ideal gas thermometers Aand Buse oxygen and hydrogen respectively. The following observations are made:
| Temperature | Pressure thermometer A | Pressure thermometer B |
| Triple-point of water | 1.250 × 105 Pa | 0.200 × 105 Pa |
| Normal melting point of sulphur | 1.797 × 105 Pa | 0.287 × 105 Pa |
(a) What is the absolute temperature of the normal melting point of sulphur as read by thermometers Aand B?
(b) What do you think is the reason behind the slight difference in answers of thermometers Aand B? (The thermometers are not faulty). What further procedure is needed in the experiment to reduce the discrepancy between the two readings?
Advertisements
उत्तर १
a)
Triple point of water, T = 273.16 K.
At this temperature, pressure in thermometer A, PA = 1.250 × 105 Pa
Let T1 be the normal melting point of sulphur.
At this temperature, pressure in thermometer A, P1 = 1.797 × 105 Pa
According to Charles’ law, we have the relation:
`P_A/T = P_1/T_1`
`:. T_1 =( P_1T)/P_A = (1.797 xx 20^(5) xx 273.16)/(1.250xx10^5)`
= 392.69 K
Therefore, the absolute temperature of the normal melting point of sulphur as read by thermometer A is 392.69 K.
At triple point 273.16 K, the pressure in thermometer B, PB = 0.200 × 105 Pa
At temperature T1, the pressure in thermometer B, P2 = 0.287 × 105 Pa
According to Charles’ law, we can write the relation:
`P_B/T = P_1/T_1`
`(0.200xx10^5)/273.16 = (0.287 xx 10^5)/T_1`
`:. T_1 = (0.287xx10^5)/(0.200xx10^5) xx 273.16 = 391.98 K`
Therefore, the absolute temperature of the normal melting point of sulphur as read by thermometer B is 391.98 K.
b) The oxygen and hydrogen gas present in thermometers A and B respectively are not perfect ideal gases. Hence, there is a slight difference between the readings of thermometers A and B.
To reduce the discrepancy between the two readings, the experiment should be carried under low pressure conditions. At low pressure, these gases behave as perfect ideal gases.
उत्तर २
Let T be the melting point of sulphur for thermometer A
`P_"tr" = 1.250 xx 10^5 Pa`; `P = 1.797 xx 10^5 Pa`
Now `T_A = T_(tr) xx P/P_"tr"`
`T_A = (273.16 xx 1.797 xx 10^5)/(.250xx10^5)k = 392.69 K`
For thermometer b
`P_"tr" = 0.200 xx 10^5 Pa`; `P = 0.287 xx 10^5 `Pa
`T_B = = T_"tr" xx P/P_"tr" = (273.16 xx 0.287 xx 10^5)/(0.200xx10^5) K`
b) The value of the melting point of sulphur found from the two thermometers differ slightly due to the reason that in practice, the gases do not behave strictly as perfect gases i.e., gases are not perfectly ideal.
To reduce the discrepency, readings should be taken for lower and lower pressures and the plot between temperature measured versus absolute pressure of the gas at triple point should be extrapolated to obtain the temperature in the limit pressure tends to zero (if P —> 0), when the gases approach ideal gas behaviour.
APPEARS IN
संबंधित प्रश्न
The triple points of neon and carbon dioxide are 24.57 K and 216.55 K respectively. Express these temperatures on the Celsius and Fahrenheit scales.
Two absolute scales A and B have triple points of water defined to be 200 A and 350 B. What is the relation between TA and TB?
Answer the following:
The triple-point of water is a standard fixed point in modern thermometry. Why? What is wrong in taking the melting point of ice and the boiling point of water as standard fixed points (as was originally done in the Celsius scale)?
In defining the ideal gas temperature scale, it is assumed that the pressure of the gas at constant volume is proportional to the temperature T. How can we verify whether this is true or not? Do we have to apply the kinetic theory of gases? Do we have to depend on experimental result that the pressure is proportional to temperature?
Consider the following statements.
(A) The coefficient of linear expansion has dimension K–1.
(B) The coefficient of volume expansion has dimension K–1.
If the temperature of a uniform rod is slightly increased by ∆t, its moment of inertia I about a perpendicular bisector increases by
Which of the following pairs represent units of the same physical quantity?
A constant-volume thermometer registers a pressure of 1.500 × 104 Pa at the triple point of water and a pressure of 2.050 × 104 Pa at the normal boiling point. What is the temperature at the normal boiling point?
The pressure measured by a constant volume gas thermometer is 40 kPa at the triple point of water. What will be the pressure measured at the boiling point of water (100°C)?
The pressure of the gas in a constant volume gas thermometer is 70 kPa at the ice point. Find the pressure at the steam point.
An aluminium vessel of mass 0.5 kg contains 0.2 kg of water at 20°C. A block of iron of mass 0.2 kg at 100°C is gently put into the water. Find the equilibrium temperature of the mixture. Specific heat capacities of aluminium, iron and water are 910 J kg−1 K−1, 470 J kg−1 K−1 and 4200 J kg−1 K−1 respectively.
The pressures of the gas in a constant volume gas thermometer are 80 cm, 90 cm and 100 cm of mercury at the ice point, the steam point and in a heated wax bath, respectively. Find the temperature of the wax bath.
In a Callender's compensated constant pressure air thermometer, the volume of the bulb is 1800 cc. When the bulb is kept immersed in a vessel, 200 cc of mercury has to be poured out. Calculate the temperature of the vessel.
Two metre scales, one of steel and the other of aluminium, agree at 20°C. Calculate the ratio aluminium-centimetre/steel-centimetre at (a) 0°C, (b) 40°C and (c) 100°C. α for steel = 1.1 × 10–5 °C–1 and for aluminium = 2.3 × 10–5°C–1.
A metre scale is made up of steel and measures correct length at 16°C. What will be the percentage error if this scale is used (a) on a summer day when the temperature is 46°C and (b) on a winter day when the temperature is 6°C? Coefficient of linear expansion of steel = 11 × 10–6 °C–1.
A metre scale made of steel reads accurately at 20°C. In a sensitive experiment, distances accurate up to 0.055 mm in 1 m are required. Find the range of temperature in which the experiment can be performed with this metre scale. Coefficient of linear expansion of steel = 11 × 10–6 °C–1.
A glass vessel measures exactly 10 cm × 10 cm × 10 cm at 0°C. It is filled completely with mercury at this temperature. When the temperature is raised to 10°C, 1.6 cm3 of mercury overflows. Calculate the coefficient of volume expansion of mercury. Coefficient of linear expansion of glass = 6.5 × 10–1 °C–1.
A copper cube of mass 200 g slides down on a rough inclined plane of inclination 37° at a constant speed. Assume that any loss in mechanical energy goes into the copper block as thermal energy. Find the increase in the temperature of the block as it slides down through 60 cm. Specific heat capacity of copper = 420 J kg−1 K−1.
Two steel rods and an aluminium rod of equal length l0 and equal cross-section are joined rigidly at their ends, as shown in the figure below. All the rods are in a state of zero tension at 0°C. Find the length of the system when the temperature is raised to θ. Coefficient of linear expansion of aluminium and steel are αa and αs, respectively. Young's modulus of aluminium is Ya and of steel is Ys.
| Steel |
| Aluminium |
| Steel |
A torsional pendulum consists of a solid disc connected to a thin wire (α = 2.4 × 10–5°C–1) at its centre. Find the percentage change in the time period between peak winter (5°C) and peak summer (45°C).
A circular disc made of iron is rotated about its axis at a constant velocity ω. Calculate the percentage change in the linear speed of a particle of the rim as the disc is slowly heated from 20°C to 50°C, keeping the angular velocity constant. Coefficient of linear expansion of iron = 1.2 × 10–5 °C–1.
Answer the following question.
How a thermometer is calibrated?
Solve the following problem.
In a random temperature scale X, water boils at 200 °X and freezes at 20 °X. Find the boiling point of a liquid in this scale if it boils at 62 °C.
If the temperature on the Fahrenheit scale is 140 °F, then the same temperature on the Kelvin scale will be:
Calculate the temperature which has same numeral value on celsius and Fahrenheit scale.
At what temperature do the Celsius and Fahrenheit scales show the same reading?
Which thermometer is considered the most accurate?
A wall that allows free exchange of heat between two systems is called ______.
Convert 37 °C (normal body temperature) to Kelvin.
Which of the following correctly describes an adiabatic wall?
A platinum wire is used as the thermometric substance in a resistance thermometer. What is the thermometric property being utilised here?
