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Fluorine reacts with ice and results in the change: HX2O(s)+FX2(g)⟶HF(g)+HOF(g) Justify that this reaction is a redox reaction.

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प्रश्न

Fluorine reacts with ice and results in the change: \[\ce{H2O(s) + F2(g) → HF(g) + HOF(g)}\]

Justify that this reaction is a redox reaction.

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उत्तर

Let us write the oxidation number of each atom involved in the given reaction above its symbol as:
+1 -2         0              +1 -1        +1 -2 +1
\[\ce{H2O(s) + F2(g) → HF(g) + HOF(g)}\]

Here, we have observed that the oxidation number of F increases from 0 in F2 to +1 in HOF. Also, the oxidation number decreases from 0 in Fto –1 in HF. Thus, in the above reaction, F is both oxidized and reduced.
Hence, the given reaction is a redox reaction.

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अध्याय 7: Redox Reactions - EXERCISES [पृष्ठ २८०]

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एनसीईआरटी Chemistry - Part 1 and 2 [English] Class 11
अध्याय 7 Redox Reactions
EXERCISES | Q 8.4 | पृष्ठ २८०

संबंधित प्रश्न

Justify that the following reaction is redox reaction:

\[\ce{Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)}\]


Justify that the following reaction is redox reaction:

\[\ce{4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)}\]


Suggest a list of the substances where carbon can exhibit oxidation states from –4 to +4 and nitrogen from –3 to +5.


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)}\]


Consider the reactions:

  1. \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
  2. \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
  3. \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
  4. \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]

What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?


What sorts of informations can you draw from the following reaction ?

\[\ce{{(CN)}_{2(g)} + 2OH-_{(aq)} -> CN-_{(aq)} + CNO-_{(aq)} + H_2O_{(l)}}\]


Refer to the periodic table given in your book and now answer the following questions:

Select the possible non-metals that can show disproportionation reaction.


Refer to the periodic table given in your book and now answer the following question:

Select three metals that can show disproportionation reaction.


Which of the following is not an example of redox reaction?


Identify disproportionation reaction


Assertion (A): Redox couple is the combination of oxidised and reduced form of a substance involved in an oxidation or reduction half cell.

Reason (R): In the representation \[\ce{E^Θ_{Fe^{3+}/Fe^{2+}}}\] and \[\ce{E^Θ_{Cu^{2+}/Cu}, Fe^{3+}/Fe^{2+}}\] and \[\ce{Cu^{2+}/Cu}\] are redox couples.


Write redox couples involved in the reactions given.

\[\ce{Cu + Zn^{2+} ->Cu^{2+} + Zn}\]


Find out the oxidation number of chlorine in the following compounds and arrange them in increasing order of oxidation number of chlorine.

\[\ce{NaClO4, NaClO3, NaClO, KClO2, Cl2O7, ClO3, Cl2O, NaCl, Cl2 , ClO2}\].

Which oxidation state is not present in any of the above compounds?


Which of the following statement is CORRECT for the decomposition reaction of KClO3

\[\ce{2KClO3 → 2KCl +3O2}\]


Which of the following reactions is the metal displacement reaction? Choose the right option.


An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)


In an experiment O3 undergo decomposition as \[\ce{O3 -> O2 + O}\] by the radiations of wavelength 310 Å. The total energy falling on the O3 gas molecules is 2.4 × 1026 eV and quantum yield of the reaction is 0.2.

The volume strength of the H2O2 solution which is obtained from reaction of 1 l H2O and nascent oxygen [O] obtained from the above reactions is (Assuming no change in volume of H2O)

\[\ce{H2O + O -> H2O2}\]

[Given: Na (Avogadro's No.) = 6 × 1023]


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