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Explain, giving reasons, which of the following sets of quantum numbers are not possible. a. n = 0, l = 0, ml = 0, ms = + ½ b. n = 1, l = 0, ml = 0, ms = – ½ c. n = 1, l = 1, ml = 0, ms = + ½ - Chemistry

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प्रश्न

Explain, giving reasons, which of the following sets of quantum numbers are not possible.

  1. n = 0, l = 0, ml = 0, ms = + ½
  2. n = 1, l = 0, ml = 0, ms = – ½
  3. n = 1, l = 1, ml = 0, ms = + ½
  4. n = 2, l = 1, ml = 0, ms = – ½
  5. n = 3, l = 3, ml = –3, ms = + ½
  6. n = 3, l = 1, ml = 0, ms = + ½
संख्यात्मक
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उत्तर

a. n = 0, l = 0, mₗ = 0, mₛ = +½

Not possible, because n cannot be 0.

b. n = 1, l = 0, mₗ = 0, mₛ = –½

Possible, because all values follow rules (l < n, mₗ = 0, valid mₛ).

c. n = 1, l = 1, mₗ = 0, mₛ = +½

Not possible, because for n = 1, l must be 0 (since l = 0 to n – 1).

d. n = 2, l = 1, mₗ = 0, mₛ = –½

Possible, all values valid.

e. n = 3, l = 3, mₗ = –3, mₛ = +½

Not possible, because l cannot be equal to n; it must be less than n.

f. n = 3, l = 1, mₗ = 0, mₛ = +½

Possible, all values valid.

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